An evaluation of cation exchange capacity methods for acid tropical soils

The cation exchange capacity (GEC) of soil is an important criteria for assessing soil fertility beside its use in soil classification. Seven methods, namely, (1) BaCl2 - triethanolamine of BaCl2 - TEA (PH 8.2), (2) NH40Ac (PH 7.0) - leaching, (3) NH40Ac (PH 7.0) - shaking, (4) compulsive exchan...

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Main Authors: Ishak, Cek Fauziah, I., Jamilah, Syed Rastan, Syed Omar
Format: Article
Language:English
Published: Universiti Putra Malaysia Press 1997
Online Access:http://psasir.upm.edu.my/id/eprint/3614/
http://psasir.upm.edu.my/id/eprint/3614/1/An_Evaluation_of_Cation_Exchange_Capacity_Methods_for_Acid.pdf
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author Ishak, Cek Fauziah
I., Jamilah
Syed Rastan, Syed Omar
author_facet Ishak, Cek Fauziah
I., Jamilah
Syed Rastan, Syed Omar
author_sort Ishak, Cek Fauziah
building UPM Institutional Repository
collection Online Access
description The cation exchange capacity (GEC) of soil is an important criteria for assessing soil fertility beside its use in soil classification. Seven methods, namely, (1) BaCl2 - triethanolamine of BaCl2 - TEA (PH 8.2), (2) NH40Ac (PH 7.0) - leaching, (3) NH40Ac (PH 7.0) - shaking, (4) compulsive exchange method of Gillman (1979) (GECcd, (5) modified compulsive exchange method of Gillman (1986) (CEC3, (6) Summation of Ca from method 5 with 1 M NH4 NO3 exchangeable Al (CECtotal and (7) summation of NH40Ac (PH 7.0) exchangeable bases with 1 M KCl exchangeable Al (CECsum) were used to determine and compare the CEC values of five acid tropical soils. All methods gave different CEC values which followed the order BaCl2 - TEA> NH40Ac shaking = NH40Ac leaching> CECsum = CECto tal > CECCE = CECB• Methods with pH conditions close to field situations gave much lower CEC values than the buffered methods. The buffered methods generate charge on the variable-charge colloids, thus resulting in inflated CEC values, while the unbuffered methods do not. There is a high correlation between BaCl2 - TEA and NH40Ac (PH 7. 0) leaching method; CECCE and CECsum; and, CECB and CECtotal Amongst the methods evaluated, the NH40Ac (PH 7.0) leaching is recommended in routine soil analyses for classification purposes while CECsum is recommended for agronomic evaluation.
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spelling upm-36142015-09-07T03:16:21Z http://psasir.upm.edu.my/id/eprint/3614/ An evaluation of cation exchange capacity methods for acid tropical soils Ishak, Cek Fauziah I., Jamilah Syed Rastan, Syed Omar The cation exchange capacity (GEC) of soil is an important criteria for assessing soil fertility beside its use in soil classification. Seven methods, namely, (1) BaCl2 - triethanolamine of BaCl2 - TEA (PH 8.2), (2) NH40Ac (PH 7.0) - leaching, (3) NH40Ac (PH 7.0) - shaking, (4) compulsive exchange method of Gillman (1979) (GECcd, (5) modified compulsive exchange method of Gillman (1986) (CEC3, (6) Summation of Ca from method 5 with 1 M NH4 NO3 exchangeable Al (CECtotal and (7) summation of NH40Ac (PH 7.0) exchangeable bases with 1 M KCl exchangeable Al (CECsum) were used to determine and compare the CEC values of five acid tropical soils. All methods gave different CEC values which followed the order BaCl2 - TEA> NH40Ac shaking = NH40Ac leaching> CECsum = CECto tal > CECCE = CECB• Methods with pH conditions close to field situations gave much lower CEC values than the buffered methods. The buffered methods generate charge on the variable-charge colloids, thus resulting in inflated CEC values, while the unbuffered methods do not. There is a high correlation between BaCl2 - TEA and NH40Ac (PH 7. 0) leaching method; CECCE and CECsum; and, CECB and CECtotal Amongst the methods evaluated, the NH40Ac (PH 7.0) leaching is recommended in routine soil analyses for classification purposes while CECsum is recommended for agronomic evaluation. Universiti Putra Malaysia Press 1997 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/3614/1/An_Evaluation_of_Cation_Exchange_Capacity_Methods_for_Acid.pdf Ishak, Cek Fauziah and I., Jamilah and Syed Rastan, Syed Omar (1997) An evaluation of cation exchange capacity methods for acid tropical soils. Pertanika Journal of Tropical Agricultural Science, 20 (2/3). pp. 113-119. ISSN 0126-6128
spellingShingle Ishak, Cek Fauziah
I., Jamilah
Syed Rastan, Syed Omar
An evaluation of cation exchange capacity methods for acid tropical soils
title An evaluation of cation exchange capacity methods for acid tropical soils
title_full An evaluation of cation exchange capacity methods for acid tropical soils
title_fullStr An evaluation of cation exchange capacity methods for acid tropical soils
title_full_unstemmed An evaluation of cation exchange capacity methods for acid tropical soils
title_short An evaluation of cation exchange capacity methods for acid tropical soils
title_sort evaluation of cation exchange capacity methods for acid tropical soils
url http://psasir.upm.edu.my/id/eprint/3614/
http://psasir.upm.edu.my/id/eprint/3614/1/An_Evaluation_of_Cation_Exchange_Capacity_Methods_for_Acid.pdf