Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting

The incorporation of reduced graphene oxide (rGO) on a TiO2 surface had been demonstrated to be an effective method to enhance the photoelectrochemical performance. A TiO2–rGO thin film was fabricated by depositing TiO2 on ITO using an aerosol-assisted chemical vapor deposition method and GO dip-coa...

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Main Authors: Jumeri, F. A., Lim, Hong Ngee, Zainal, Zulkarnain, Huang, Nay Ming, Pandikumar, Alagarsamy
Format: Article
Language:English
Published: Elsevier 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35858/
http://psasir.upm.edu.my/id/eprint/35858/1/Titanium%20dioxide-reduced%20graphene%20oxide%20thin%20film%20for%20photoelectrochemical%20water%20splitting.pdf
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author Jumeri, F. A.
Lim, Hong Ngee
Zainal, Zulkarnain
Huang, Nay Ming
Pandikumar, Alagarsamy
author_facet Jumeri, F. A.
Lim, Hong Ngee
Zainal, Zulkarnain
Huang, Nay Ming
Pandikumar, Alagarsamy
author_sort Jumeri, F. A.
building UPM Institutional Repository
collection Online Access
description The incorporation of reduced graphene oxide (rGO) on a TiO2 surface had been demonstrated to be an effective method to enhance the photoelectrochemical performance. A TiO2–rGO thin film was fabricated by depositing TiO2 on ITO using an aerosol-assisted chemical vapor deposition method and GO dip-coating, followed by thermal reduction of the GO layer. The fabricated thin film was characterized using XRD and FESEM techniques. The photoelectrotrochemical performance of the TiO2–rGO thin film was investigated under the illumination of simulated solar light. The TiO2–rGO showed a higher photocurrent response (80.2 µA) than bare TiO2 (13.1 µA). This improved photoelectrochemical performance was due to the rGO, which increased the electron transport and thereby minimized the charge recombination process. The TiO2–rGO thin film showed good stability, even after being subjected to 1000 voltammetric cycles, and the rGO sheets remained adhered to the surface of the TiO2 thin film.
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publishDate 2014
publisher Elsevier
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spelling upm-358582016-03-04T00:33:02Z http://psasir.upm.edu.my/id/eprint/35858/ Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting Jumeri, F. A. Lim, Hong Ngee Zainal, Zulkarnain Huang, Nay Ming Pandikumar, Alagarsamy The incorporation of reduced graphene oxide (rGO) on a TiO2 surface had been demonstrated to be an effective method to enhance the photoelectrochemical performance. A TiO2–rGO thin film was fabricated by depositing TiO2 on ITO using an aerosol-assisted chemical vapor deposition method and GO dip-coating, followed by thermal reduction of the GO layer. The fabricated thin film was characterized using XRD and FESEM techniques. The photoelectrotrochemical performance of the TiO2–rGO thin film was investigated under the illumination of simulated solar light. The TiO2–rGO showed a higher photocurrent response (80.2 µA) than bare TiO2 (13.1 µA). This improved photoelectrochemical performance was due to the rGO, which increased the electron transport and thereby minimized the charge recombination process. The TiO2–rGO thin film showed good stability, even after being subjected to 1000 voltammetric cycles, and the rGO sheets remained adhered to the surface of the TiO2 thin film. Elsevier 2014-11 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/35858/1/Titanium%20dioxide-reduced%20graphene%20oxide%20thin%20film%20for%20photoelectrochemical%20water%20splitting.pdf Jumeri, F. A. and Lim, Hong Ngee and Zainal, Zulkarnain and Huang, Nay Ming and Pandikumar, Alagarsamy (2014) Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting. Ceramics International, 40 (9 pt.B). pp. 15159-15165. ISSN 0272-8842; ESSN: 1873-3956 http://www.sciencedirect.com/science/article/pii/S0272884214010293 10.1016/j.ceramint.2014.06.130
spellingShingle Jumeri, F. A.
Lim, Hong Ngee
Zainal, Zulkarnain
Huang, Nay Ming
Pandikumar, Alagarsamy
Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting
title Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting
title_full Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting
title_fullStr Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting
title_full_unstemmed Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting
title_short Titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting
title_sort titanium dioxide-reduced graphene oxide thin film for photoelectrochemical water splitting
url http://psasir.upm.edu.my/id/eprint/35858/
http://psasir.upm.edu.my/id/eprint/35858/
http://psasir.upm.edu.my/id/eprint/35858/
http://psasir.upm.edu.my/id/eprint/35858/1/Titanium%20dioxide-reduced%20graphene%20oxide%20thin%20film%20for%20photoelectrochemical%20water%20splitting.pdf