Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems

ZnO micro and nanostructures were grown on copper coated silicon substrates using two different systems: an opened system (both ends opened tube) and a closed system (one closed end tube). The thermodynamic conditions of the systems made a significant difference in boundary layer and super-saturatio...

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Main Authors: Kamalianfar, Ahmad, Shaari, Abdul Halim, Zak, Ali Khorsand
Format: Article
Published: Elsevier 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35580/
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author Kamalianfar, Ahmad
Shaari, Abdul Halim
Zak, Ali Khorsand
author_facet Kamalianfar, Ahmad
Shaari, Abdul Halim
Zak, Ali Khorsand
author_sort Kamalianfar, Ahmad
building UPM Institutional Repository
collection Online Access
description ZnO micro and nanostructures were grown on copper coated silicon substrates using two different systems: an opened system (both ends opened tube) and a closed system (one closed end tube). The thermodynamic conditions of the systems made a significant difference in boundary layer and super-saturation between the systems. The results indicate that diffusion of the gaseous species through the boundary layers at low and high pressures controls the final formation of the morphologies. The ZnO nanostructures which have been grown in a restricted place have larger diameters and lengths. The structure of the products was analyzed by X-ray diffractometer (XRD) and it was found that the good crystalline quality of the samples was obtained in a closed system. To study the optical properties, photoluminescence (PL) and ultra violet–visible (UV–vis) spectroscopy were employed. It was observed that a decrease in the growth temperature of the opened system caused a broad and dominant visible emission covering the blue and green emission in the PL spectra.
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institution Universiti Putra Malaysia
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publishDate 2014
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spelling upm-355802016-01-18T01:17:27Z http://psasir.upm.edu.my/id/eprint/35580/ Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems Kamalianfar, Ahmad Shaari, Abdul Halim Zak, Ali Khorsand ZnO micro and nanostructures were grown on copper coated silicon substrates using two different systems: an opened system (both ends opened tube) and a closed system (one closed end tube). The thermodynamic conditions of the systems made a significant difference in boundary layer and super-saturation between the systems. The results indicate that diffusion of the gaseous species through the boundary layers at low and high pressures controls the final formation of the morphologies. The ZnO nanostructures which have been grown in a restricted place have larger diameters and lengths. The structure of the products was analyzed by X-ray diffractometer (XRD) and it was found that the good crystalline quality of the samples was obtained in a closed system. To study the optical properties, photoluminescence (PL) and ultra violet–visible (UV–vis) spectroscopy were employed. It was observed that a decrease in the growth temperature of the opened system caused a broad and dominant visible emission covering the blue and green emission in the PL spectra. Elsevier 2014-03 Article PeerReviewed Kamalianfar, Ahmad and Shaari, Abdul Halim and Zak, Ali Khorsand (2014) Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems. Ceramics International, 40 (2). pp. 3193-3198. ISSN 0272-8842; ESSN: 1873-3956 http://www.sciencedirect.com/science/article/pii/S0272884213012261 10.1016/j.ceramint.2013.09.123
spellingShingle Kamalianfar, Ahmad
Shaari, Abdul Halim
Zak, Ali Khorsand
Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems
title Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems
title_full Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems
title_fullStr Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems
title_full_unstemmed Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems
title_short Synthesis of ZnO/Cu micro and nanostructures via a vapor phase transport method using different tube systems
title_sort synthesis of zno/cu micro and nanostructures via a vapor phase transport method using different tube systems
url http://psasir.upm.edu.my/id/eprint/35580/
http://psasir.upm.edu.my/id/eprint/35580/
http://psasir.upm.edu.my/id/eprint/35580/