Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
In order to design sustainable materials from vegetable oil-based fatty acids, we propose herewith a method to obtain unsaturated dicarboxylic acids as a polymerizable monomer through metathesis reaction of oleic and linoleic acids with the 2nd generation Grubbs catalyst. Subsequently, functional gr...
| Main Authors: | , , , , , |
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| Format: | Article |
| Published: |
Chemical Society of Japan
2014
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| Online Access: | http://psasir.upm.edu.my/id/eprint/35576/ |
| _version_ | 1848848093873700864 |
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| author | Abd. Rahim, Noor Farisha Watanabe, Kohtaro Ariffin, Hidayah Andou, Yoshito Hassan, Mohd Ali Shirai, Yoshihito |
| author_facet | Abd. Rahim, Noor Farisha Watanabe, Kohtaro Ariffin, Hidayah Andou, Yoshito Hassan, Mohd Ali Shirai, Yoshihito |
| author_sort | Abd. Rahim, Noor Farisha |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | In order to design sustainable materials from vegetable oil-based fatty acids, we propose herewith a method to obtain unsaturated dicarboxylic acids as a polymerizable monomer through metathesis reaction of oleic and linoleic acids with the 2nd generation Grubbs catalyst. Subsequently, functional green polyester was produced from dicarboxylic acids and aromatic diol. Dicarboxylic acid having similar structure i.e., octadec-9-enedioic acid was successfully obtained from metathesis of both oleic and linoleic acids. Condensation polymerization of octadec-9-enedioic acid with 1,6-hexanediol and 4,4′-biphenol was carried out and it was shown that polymer with aromatic backbone had higher glass-transition temperature than aliphatic polyester. |
| first_indexed | 2025-11-15T09:29:02Z |
| format | Article |
| id | upm-35576 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-15T09:29:02Z |
| publishDate | 2014 |
| publisher | Chemical Society of Japan |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-355762016-01-18T01:09:04Z http://psasir.upm.edu.my/id/eprint/35576/ Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester Abd. Rahim, Noor Farisha Watanabe, Kohtaro Ariffin, Hidayah Andou, Yoshito Hassan, Mohd Ali Shirai, Yoshihito In order to design sustainable materials from vegetable oil-based fatty acids, we propose herewith a method to obtain unsaturated dicarboxylic acids as a polymerizable monomer through metathesis reaction of oleic and linoleic acids with the 2nd generation Grubbs catalyst. Subsequently, functional green polyester was produced from dicarboxylic acids and aromatic diol. Dicarboxylic acid having similar structure i.e., octadec-9-enedioic acid was successfully obtained from metathesis of both oleic and linoleic acids. Condensation polymerization of octadec-9-enedioic acid with 1,6-hexanediol and 4,4′-biphenol was carried out and it was shown that polymer with aromatic backbone had higher glass-transition temperature than aliphatic polyester. Chemical Society of Japan 2014 Article PeerReviewed Abd. Rahim, Noor Farisha and Watanabe, Kohtaro and Ariffin, Hidayah and Andou, Yoshito and Hassan, Mohd Ali and Shirai, Yoshihito (2014) Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester. Chemistry Letters, 43 (9). pp. 1517-1519. ISSN 0366-7022; ESSN: 1348-0715 https://www.jstage.jst.go.jp/article/cl/43/9/43_140471/_article 10.1246/cl.140471 |
| spellingShingle | Abd. Rahim, Noor Farisha Watanabe, Kohtaro Ariffin, Hidayah Andou, Yoshito Hassan, Mohd Ali Shirai, Yoshihito Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester |
| title | Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester |
| title_full | Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester |
| title_fullStr | Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester |
| title_full_unstemmed | Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester |
| title_short | Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester |
| title_sort | synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester |
| url | http://psasir.upm.edu.my/id/eprint/35576/ http://psasir.upm.edu.my/id/eprint/35576/ http://psasir.upm.edu.my/id/eprint/35576/ |