Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells

A novel nano-bio composite polypyrrole (PPy)/kappa-carrageenan(KC) was fabricated and characterized for application as a cathode catalyst in a microbial fuel cell (MFC). High resolution SEM and TEM verified the bud-like shape and uniform distribution of the PPy in the KC matrix. X-ray diffraction (X...

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Main Authors: Esmaeili, Chakavak, Ghasemi, Mostafa, Lee, Yook Heng, Hassan, Sedky H. A., Abdi, Mahnaz M., Wan Daud, Wan Ramli, Ilbeygi, Hamid, Ismail, Ahmad Fauzi
Format: Article
Published: Elsevier 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35564/
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author Esmaeili, Chakavak
Ghasemi, Mostafa
Lee, Yook Heng
Hassan, Sedky H. A.
Abdi, Mahnaz M.
Wan Daud, Wan Ramli
Ilbeygi, Hamid
Ismail, Ahmad Fauzi
author_facet Esmaeili, Chakavak
Ghasemi, Mostafa
Lee, Yook Heng
Hassan, Sedky H. A.
Abdi, Mahnaz M.
Wan Daud, Wan Ramli
Ilbeygi, Hamid
Ismail, Ahmad Fauzi
author_sort Esmaeili, Chakavak
building UPM Institutional Repository
collection Online Access
description A novel nano-bio composite polypyrrole (PPy)/kappa-carrageenan(KC) was fabricated and characterized for application as a cathode catalyst in a microbial fuel cell (MFC). High resolution SEM and TEM verified the bud-like shape and uniform distribution of the PPy in the KC matrix. X-ray diffraction (XRD) has approved the amorphous structure of the PPy/KC as well. The PPy/KC nano-bio composites were then studied as an electrode material, due to their oxygen reduction reaction (ORR) ability as the cathode catalyst in the MFC and the results were compared with platinum (Pt) as the most common cathode catalyst. The produced power density of the PPy/KC was 72.1 mW/m2 while it was 46.8 mW/m2 and 28.8 mW/m2 for KC and PPy individually. The efficiency of the PPy/KC electrode system is slightly lower than a Pt electrode (79.9 mW/m2) but due to the high cost of Pt electrodes, the PPy/KC electrode system has potential to be an alternative electrode system for MFCs.
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institution Universiti Putra Malaysia
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publishDate 2014
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spelling upm-355642016-01-14T00:03:54Z http://psasir.upm.edu.my/id/eprint/35564/ Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells Esmaeili, Chakavak Ghasemi, Mostafa Lee, Yook Heng Hassan, Sedky H. A. Abdi, Mahnaz M. Wan Daud, Wan Ramli Ilbeygi, Hamid Ismail, Ahmad Fauzi A novel nano-bio composite polypyrrole (PPy)/kappa-carrageenan(KC) was fabricated and characterized for application as a cathode catalyst in a microbial fuel cell (MFC). High resolution SEM and TEM verified the bud-like shape and uniform distribution of the PPy in the KC matrix. X-ray diffraction (XRD) has approved the amorphous structure of the PPy/KC as well. The PPy/KC nano-bio composites were then studied as an electrode material, due to their oxygen reduction reaction (ORR) ability as the cathode catalyst in the MFC and the results were compared with platinum (Pt) as the most common cathode catalyst. The produced power density of the PPy/KC was 72.1 mW/m2 while it was 46.8 mW/m2 and 28.8 mW/m2 for KC and PPy individually. The efficiency of the PPy/KC electrode system is slightly lower than a Pt electrode (79.9 mW/m2) but due to the high cost of Pt electrodes, the PPy/KC electrode system has potential to be an alternative electrode system for MFCs. Elsevier 2014-12-19 Article PeerReviewed Esmaeili, Chakavak and Ghasemi, Mostafa and Lee, Yook Heng and Hassan, Sedky H. A. and Abdi, Mahnaz M. and Wan Daud, Wan Ramli and Ilbeygi, Hamid and Ismail, Ahmad Fauzi (2014) Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells. Carbohydrate Polymers, 114. pp. 253-259. ISSN 0144-8617; ESSN: 1879-1344 http://www.sciencedirect.com/science/article/pii/S0144861714007620 10.1016/j.carbpol.2014.07.072
spellingShingle Esmaeili, Chakavak
Ghasemi, Mostafa
Lee, Yook Heng
Hassan, Sedky H. A.
Abdi, Mahnaz M.
Wan Daud, Wan Ramli
Ilbeygi, Hamid
Ismail, Ahmad Fauzi
Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells
title Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells
title_full Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells
title_fullStr Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells
title_full_unstemmed Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells
title_short Synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells
title_sort synthesis and application of polypyrrole/carrageenan nano-bio composite as a cathode catalyst in microbial fuel cells
url http://psasir.upm.edu.my/id/eprint/35564/
http://psasir.upm.edu.my/id/eprint/35564/
http://psasir.upm.edu.my/id/eprint/35564/