Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell

We report a simple and convenient method for the preparation of Ag/TiO2 thin films supported on indium tin oxide, which was achieved by sonochemical deposition of Ag+ on aerosol-assisted chemical vapour deposited TiO2 thin films. Posttreatment was performed on the film by immersion in HCl. The as-pr...

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Main Authors: Lim, Su Pei, Huang, Nay Ming, Lim, Hong Ngee, Mazhar, Muhammad
Format: Article
Language:English
Published: Hindawi Publishing Corporation 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35541/
http://psasir.upm.edu.my/id/eprint/35541/1/Surface%20Modification%20of%20Aerosol-Assisted%20CVD%20Produced%20TiO2.pdf
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author Lim, Su Pei
Huang, Nay Ming
Lim, Hong Ngee
Mazhar, Muhammad
author_facet Lim, Su Pei
Huang, Nay Ming
Lim, Hong Ngee
Mazhar, Muhammad
author_sort Lim, Su Pei
building UPM Institutional Repository
collection Online Access
description We report a simple and convenient method for the preparation of Ag/TiO2 thin films supported on indium tin oxide, which was achieved by sonochemical deposition of Ag+ on aerosol-assisted chemical vapour deposited TiO2 thin films. Posttreatment was performed on the film by immersion in HCl. The as-prepared composite film was characterised by X-ray diffraction, ultraviolet-visible absorption spectroscopy, Raman spectroscopy, and field emission scanning electron microscopy. The photoelectrochemical measurements and characterisation showed approximately fivefold increase in photocurrent density generation and approximately sevenfold enhancement in dye sensitiser solar cell (DSSC) conversion efficiency, which was achieved after modification of the TiO2 film with HCl posttreatment and Ag particle deposition. The improved photocurrent density of 933.30 A/cm2, as well as DSSC power conversion efficiency of 3.63% with high stability, is an indication that the as-synthesised thin film is a potential candidate for solar energy conversion applications.
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institution Universiti Putra Malaysia
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publishDate 2014
publisher Hindawi Publishing Corporation
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spelling upm-355412016-03-03T14:11:00Z http://psasir.upm.edu.my/id/eprint/35541/ Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell Lim, Su Pei Huang, Nay Ming Lim, Hong Ngee Mazhar, Muhammad We report a simple and convenient method for the preparation of Ag/TiO2 thin films supported on indium tin oxide, which was achieved by sonochemical deposition of Ag+ on aerosol-assisted chemical vapour deposited TiO2 thin films. Posttreatment was performed on the film by immersion in HCl. The as-prepared composite film was characterised by X-ray diffraction, ultraviolet-visible absorption spectroscopy, Raman spectroscopy, and field emission scanning electron microscopy. The photoelectrochemical measurements and characterisation showed approximately fivefold increase in photocurrent density generation and approximately sevenfold enhancement in dye sensitiser solar cell (DSSC) conversion efficiency, which was achieved after modification of the TiO2 film with HCl posttreatment and Ag particle deposition. The improved photocurrent density of 933.30 A/cm2, as well as DSSC power conversion efficiency of 3.63% with high stability, is an indication that the as-synthesised thin film is a potential candidate for solar energy conversion applications. Hindawi Publishing Corporation 2014 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/35541/1/Surface%20Modification%20of%20Aerosol-Assisted%20CVD%20Produced%20TiO2.pdf Lim, Su Pei and Huang, Nay Ming and Lim, Hong Ngee and Mazhar, Muhammad (2014) Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell. International Journal of Photoenergy, 2014. art. no. 586707. pp. 1-12. ISSN 1110-662X; ESSN: 1687-529X http://www.hindawi.com/journals/ijp/2014/586707/abs/ 10.1155/2014/586707
spellingShingle Lim, Su Pei
Huang, Nay Ming
Lim, Hong Ngee
Mazhar, Muhammad
Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell
title Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell
title_full Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell
title_fullStr Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell
title_full_unstemmed Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell
title_short Surface modification of aerosol-assisted CVD produced TiO2 thin film for dye sensitised solar cell
title_sort surface modification of aerosol-assisted cvd produced tio2 thin film for dye sensitised solar cell
url http://psasir.upm.edu.my/id/eprint/35541/
http://psasir.upm.edu.my/id/eprint/35541/
http://psasir.upm.edu.my/id/eprint/35541/
http://psasir.upm.edu.my/id/eprint/35541/1/Surface%20Modification%20of%20Aerosol-Assisted%20CVD%20Produced%20TiO2.pdf