Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions

Absorption and emission spectra of Sm3+ doped lithium sodium borate (LNB) have been reported. The samples were prepared by the melt-quenching technique and characterized by X-ray diffraction (XRD), diffraction thermal analysis (DTA), Fourier transforms infrared (FTIR) spectroscopy and field emission...

Full description

Bibliographic Details
Main Authors: Dawaud, R. S. E. S., Hashim, Suhairul, Alajerami, Yasser Saleh Mustafa, Mhareb, M. H. A., Maqableh, Mazin M., Tamchek, Nizam
Format: Article
Published: World Scientific Publishing 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35491/
_version_ 1848848070251380736
author Dawaud, R. S. E. S.
Hashim, Suhairul
Alajerami, Yasser Saleh Mustafa
Mhareb, M. H. A.
Maqableh, Mazin M.
Tamchek, Nizam
author_facet Dawaud, R. S. E. S.
Hashim, Suhairul
Alajerami, Yasser Saleh Mustafa
Mhareb, M. H. A.
Maqableh, Mazin M.
Tamchek, Nizam
author_sort Dawaud, R. S. E. S.
building UPM Institutional Repository
collection Online Access
description Absorption and emission spectra of Sm3+ doped lithium sodium borate (LNB) have been reported. The samples were prepared by the melt-quenching technique and characterized by X-ray diffraction (XRD), diffraction thermal analysis (DTA), Fourier transforms infrared (FTIR) spectroscopy and field emission scanning electron microscopy (FESEM). From the thermo-grams spectrum, glass transition (Tg), crystallization (Tc) and melting temperatures (Tm) have been evaluated. Direct and indirect optical band gaps have been calculated based on the glasses UV absorption spectra. These glasses have shown strong nine absorption bands with hypersensitive transition at 1221 nm (6H5/2→4H3/2) and five emission bands for the transition at 4I7/2→6H13/2 (green color), 4I7/2→6H7/2 (orange color), 4I7/2→6H9/2 (orange color), 4I7/2→6H11/2 (red color) and 4I7/2→6H13/2 (red color) with performing an excitation of 400 nm. The oscillator strengths, refractive index, ions concentration, polaron radius and other parameters have been calculated for each dopant.
first_indexed 2025-11-15T09:28:39Z
format Article
id upm-35491
institution Universiti Putra Malaysia
institution_category Local University
last_indexed 2025-11-15T09:28:39Z
publishDate 2014
publisher World Scientific Publishing
recordtype eprints
repository_type Digital Repository
spelling upm-354912016-01-11T03:14:11Z http://psasir.upm.edu.my/id/eprint/35491/ Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions Dawaud, R. S. E. S. Hashim, Suhairul Alajerami, Yasser Saleh Mustafa Mhareb, M. H. A. Maqableh, Mazin M. Tamchek, Nizam Absorption and emission spectra of Sm3+ doped lithium sodium borate (LNB) have been reported. The samples were prepared by the melt-quenching technique and characterized by X-ray diffraction (XRD), diffraction thermal analysis (DTA), Fourier transforms infrared (FTIR) spectroscopy and field emission scanning electron microscopy (FESEM). From the thermo-grams spectrum, glass transition (Tg), crystallization (Tc) and melting temperatures (Tm) have been evaluated. Direct and indirect optical band gaps have been calculated based on the glasses UV absorption spectra. These glasses have shown strong nine absorption bands with hypersensitive transition at 1221 nm (6H5/2→4H3/2) and five emission bands for the transition at 4I7/2→6H13/2 (green color), 4I7/2→6H7/2 (orange color), 4I7/2→6H9/2 (orange color), 4I7/2→6H11/2 (red color) and 4I7/2→6H13/2 (red color) with performing an excitation of 400 nm. The oscillator strengths, refractive index, ions concentration, polaron radius and other parameters have been calculated for each dopant. World Scientific Publishing 2014-10-20 Article PeerReviewed Dawaud, R. S. E. S. and Hashim, Suhairul and Alajerami, Yasser Saleh Mustafa and Mhareb, M. H. A. and Maqableh, Mazin M. and Tamchek, Nizam (2014) Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions. International Journal of Modern Physics B, 28 (26). art. no. 1450182. pp. 1-12. ISSN 0217-9792; ESSN:1793-6578 http://www.worldscientific.com/doi/abs/10.1142/S0217979214501823 10.1142/S0217979214501823
spellingShingle Dawaud, R. S. E. S.
Hashim, Suhairul
Alajerami, Yasser Saleh Mustafa
Mhareb, M. H. A.
Maqableh, Mazin M.
Tamchek, Nizam
Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions
title Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions
title_full Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions
title_fullStr Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions
title_full_unstemmed Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions
title_short Structural and optical properties of lithium sodium borate glasses doped with Sm3+ ions
title_sort structural and optical properties of lithium sodium borate glasses doped with sm3+ ions
url http://psasir.upm.edu.my/id/eprint/35491/
http://psasir.upm.edu.my/id/eprint/35491/
http://psasir.upm.edu.my/id/eprint/35491/