Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels

Characterization Malaysian rubber-wood sawdust derived biochar (MRWSB) produced in the fixed bed pyrolysis under different temperatures (450 to 850°C) were studied for its applicability as a solid fuel. A range of analyses were carried out, including biochar oxidation reactivity , inorganic species,...

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Main Authors: Wan Ab. Karim Ghani, Wan Azlina, Da Silva, Gabriel, Alias, Azil Bahari
Format: Article
Language:English
Published: Malaysian Analytical Sciences Society 2014
Online Access:http://psasir.upm.edu.my/id/eprint/34932/
http://psasir.upm.edu.my/id/eprint/34932/1/Physico-chemical%20characterizations%20of%20sawdust-derived%20biochar%20as%20potential%20solid%20fuels.pdf
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author Wan Ab. Karim Ghani, Wan Azlina
Da Silva, Gabriel
Alias, Azil Bahari
author_facet Wan Ab. Karim Ghani, Wan Azlina
Da Silva, Gabriel
Alias, Azil Bahari
author_sort Wan Ab. Karim Ghani, Wan Azlina
building UPM Institutional Repository
collection Online Access
description Characterization Malaysian rubber-wood sawdust derived biochar (MRWSB) produced in the fixed bed pyrolysis under different temperatures (450 to 850°C) were studied for its applicability as a solid fuel. A range of analyses were carried out, including biochar oxidation reactivity , inorganic species, oxygen and hydrogen contents in the biochars, release of heteroatoms in biochar as the gaseous product, and biochar structural evolution during pyrolysis process. The results show that the optimum temperature for carbonization to obtain a char having moderately high yield was found as 450 °C. Thermogravimetric analyses (TG) shows that temperatures induces a progressively more ordered carbonaceous structure and leads to a significant changes in the biochar reactivity. The process is coupled with the loss of heteroatoms, released as dominantly carbon dioxide (C02) and carbon dioxide (CO). In addition, the elemental study of wood-derived biochar shows the higher carbon content but with low H/C and 0/C ratio suggested this material was dominated by highly aromatic structures and this were revealed in the Fourier transform infra-red (FTIR). More importantly, insignificant amount of inorganic species is evidenced in the samples.
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spelling upm-349322016-10-10T08:05:28Z http://psasir.upm.edu.my/id/eprint/34932/ Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels Wan Ab. Karim Ghani, Wan Azlina Da Silva, Gabriel Alias, Azil Bahari Characterization Malaysian rubber-wood sawdust derived biochar (MRWSB) produced in the fixed bed pyrolysis under different temperatures (450 to 850°C) were studied for its applicability as a solid fuel. A range of analyses were carried out, including biochar oxidation reactivity , inorganic species, oxygen and hydrogen contents in the biochars, release of heteroatoms in biochar as the gaseous product, and biochar structural evolution during pyrolysis process. The results show that the optimum temperature for carbonization to obtain a char having moderately high yield was found as 450 °C. Thermogravimetric analyses (TG) shows that temperatures induces a progressively more ordered carbonaceous structure and leads to a significant changes in the biochar reactivity. The process is coupled with the loss of heteroatoms, released as dominantly carbon dioxide (C02) and carbon dioxide (CO). In addition, the elemental study of wood-derived biochar shows the higher carbon content but with low H/C and 0/C ratio suggested this material was dominated by highly aromatic structures and this were revealed in the Fourier transform infra-red (FTIR). More importantly, insignificant amount of inorganic species is evidenced in the samples. Malaysian Analytical Sciences Society 2014 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/34932/1/Physico-chemical%20characterizations%20of%20sawdust-derived%20biochar%20as%20potential%20solid%20fuels.pdf Wan Ab. Karim Ghani, Wan Azlina and Da Silva, Gabriel and Alias, Azil Bahari (2014) Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels. The Malaysian Journal of Analytical Sciences, 18 (3). pp. 724-729. ISSN 1394-2506 http://www.ukm.my/mjas/new_mjas/
spellingShingle Wan Ab. Karim Ghani, Wan Azlina
Da Silva, Gabriel
Alias, Azil Bahari
Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels
title Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels
title_full Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels
title_fullStr Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels
title_full_unstemmed Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels
title_short Physico-chemical characterizations of sawdust-derived biochar as potential solid fuels
title_sort physico-chemical characterizations of sawdust-derived biochar as potential solid fuels
url http://psasir.upm.edu.my/id/eprint/34932/
http://psasir.upm.edu.my/id/eprint/34932/
http://psasir.upm.edu.my/id/eprint/34932/1/Physico-chemical%20characterizations%20of%20sawdust-derived%20biochar%20as%20potential%20solid%20fuels.pdf