Optical properties of zinc-borotellurite doped samarium

Glasses with chemical compositional {[(TeO2)0.7(B2O3)0.3}]0.7 [ZnO]0.3}1_x {Sm2O3}x, (where x=0, 0.005, 0.01, 0.02, 0.03, 0.04, 0.05 mol %); were prepared by conventional melt-quenching technique. The structural properties of the prepared glasses were determined by X-ray diffraction (XRD) analysis a...

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Main Authors: Saleh, Hajer Saad, Mohamed Kamari, Halimah, Zakaria, Azmi, Abd Azis, Muhammad Noorazlan
Format: Article
Language:English
Published: National Institute of Materials Physics, National Institute of Optoelectronics 2014
Online Access:http://psasir.upm.edu.my/id/eprint/34757/
http://psasir.upm.edu.my/id/eprint/34757/1/Optical%20properties%20of%20zinc.pdf
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author Saleh, Hajer Saad
Mohamed Kamari, Halimah
Zakaria, Azmi
Abd Azis, Muhammad Noorazlan
author_facet Saleh, Hajer Saad
Mohamed Kamari, Halimah
Zakaria, Azmi
Abd Azis, Muhammad Noorazlan
author_sort Saleh, Hajer Saad
building UPM Institutional Repository
collection Online Access
description Glasses with chemical compositional {[(TeO2)0.7(B2O3)0.3}]0.7 [ZnO]0.3}1_x {Sm2O3}x, (where x=0, 0.005, 0.01, 0.02, 0.03, 0.04, 0.05 mol %); were prepared by conventional melt-quenching technique. The structural properties of the prepared glasses were determined by X-ray diffraction (XRD) analysis and FTIR analysis. It was confirmed that the prepared glasses are amorphous. The bonding parameters of the glasses were analyzed by using FTIR analysis and were confirmed to be ionic in nature. The density, molar volume, and optical energy band gap of these glasses have been measured. The refractive index, molar refraction and polarizability of oxide ion have been estimated by using Lorentz-Lorentz relations. The optical absorption spectra of these glasses were revealed that fundamental absorption edge shifts to higher wavelengths as the content of Sm2O3 increases. The refractive index, optical energy band gap and Urbach energy had been calculated and explained.
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spelling upm-347572017-04-26T04:30:55Z http://psasir.upm.edu.my/id/eprint/34757/ Optical properties of zinc-borotellurite doped samarium Saleh, Hajer Saad Mohamed Kamari, Halimah Zakaria, Azmi Abd Azis, Muhammad Noorazlan Glasses with chemical compositional {[(TeO2)0.7(B2O3)0.3}]0.7 [ZnO]0.3}1_x {Sm2O3}x, (where x=0, 0.005, 0.01, 0.02, 0.03, 0.04, 0.05 mol %); were prepared by conventional melt-quenching technique. The structural properties of the prepared glasses were determined by X-ray diffraction (XRD) analysis and FTIR analysis. It was confirmed that the prepared glasses are amorphous. The bonding parameters of the glasses were analyzed by using FTIR analysis and were confirmed to be ionic in nature. The density, molar volume, and optical energy band gap of these glasses have been measured. The refractive index, molar refraction and polarizability of oxide ion have been estimated by using Lorentz-Lorentz relations. The optical absorption spectra of these glasses were revealed that fundamental absorption edge shifts to higher wavelengths as the content of Sm2O3 increases. The refractive index, optical energy band gap and Urbach energy had been calculated and explained. National Institute of Materials Physics, National Institute of Optoelectronics 2014-11 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/34757/1/Optical%20properties%20of%20zinc.pdf Saleh, Hajer Saad and Mohamed Kamari, Halimah and Zakaria, Azmi and Abd Azis, Muhammad Noorazlan (2014) Optical properties of zinc-borotellurite doped samarium. Chalcogenide Letters, 11 (11). pp. 553-566. ISSN 1584-8663 http://www.chalcogen.ro/index.php/journals/chalcogenide-letters/11-cl/75-volume-11-number-11-november-2014
spellingShingle Saleh, Hajer Saad
Mohamed Kamari, Halimah
Zakaria, Azmi
Abd Azis, Muhammad Noorazlan
Optical properties of zinc-borotellurite doped samarium
title Optical properties of zinc-borotellurite doped samarium
title_full Optical properties of zinc-borotellurite doped samarium
title_fullStr Optical properties of zinc-borotellurite doped samarium
title_full_unstemmed Optical properties of zinc-borotellurite doped samarium
title_short Optical properties of zinc-borotellurite doped samarium
title_sort optical properties of zinc-borotellurite doped samarium
url http://psasir.upm.edu.my/id/eprint/34757/
http://psasir.upm.edu.my/id/eprint/34757/
http://psasir.upm.edu.my/id/eprint/34757/1/Optical%20properties%20of%20zinc.pdf