Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification

Exploitation of biomass wastes gives new hopes in the exploration of clean alternative fuel source such as hydrogen energy. The application of catalysts plays a major role in the process by enhancing the production of hydrogen via reformation and tar cracking reaction. However, certain drawbacks suc...

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Main Authors: Yap, Taufiq Yun Hin, Abdul Rahim, Nur Faizal, Seenivasagam, Sivasangar, Hussein, Mohd Zobir, Ahmad, Aishah
Format: Article
Language:English
Published: John Wiley & Sons 2014
Online Access:http://psasir.upm.edu.my/id/eprint/34560/
http://psasir.upm.edu.my/id/eprint/34560/1/Modification%20of%20Malaysian%20dolomite%20using%20mechanochemical%20treatment%20via%20different%20media%20for%20oil%20palm%20fronds%20gasification.pdf
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author Yap, Taufiq Yun Hin
Abdul Rahim, Nur Faizal
Seenivasagam, Sivasangar
Hussein, Mohd Zobir
Ahmad, Aishah
author_facet Yap, Taufiq Yun Hin
Abdul Rahim, Nur Faizal
Seenivasagam, Sivasangar
Hussein, Mohd Zobir
Ahmad, Aishah
author_sort Yap, Taufiq Yun Hin
building UPM Institutional Repository
collection Online Access
description Exploitation of biomass wastes gives new hopes in the exploration of clean alternative fuel source such as hydrogen energy. The application of catalysts plays a major role in the process by enhancing the production of hydrogen via reformation and tar cracking reaction. However, certain drawbacks such as catalyst cost, deactivation, and regeneration remain unsolved in this process. In this study, we focused on potential Malaysian dolomite (Perlis) as the source of catalysts for palm frond gasification. The influences of mechanochemical treatment in three different media (air, ethanol, and water) on the catalytic activity of the material were analyzed. Important changes in the properties of the dolomite along with the high catalytic performance were noted as the results of the treatment. Notable changes in the dolomite structure and porosity were observed because of the impact of the treatment. Increment in the surface area of the catalysts boosts the H2 production and catalytic activity of dolomite. Moreover, substantial CO2 reduction was also observed during reaction as a result of the absorption capacity of treated dolomite. Thus, through mechanochemical treatment, the property of Malaysian dolomite is being greatly altered, which really suits as a potential catalyst for gasification.
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publisher John Wiley & Sons
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spelling upm-345602016-11-25T02:11:46Z http://psasir.upm.edu.my/id/eprint/34560/ Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification Yap, Taufiq Yun Hin Abdul Rahim, Nur Faizal Seenivasagam, Sivasangar Hussein, Mohd Zobir Ahmad, Aishah Exploitation of biomass wastes gives new hopes in the exploration of clean alternative fuel source such as hydrogen energy. The application of catalysts plays a major role in the process by enhancing the production of hydrogen via reformation and tar cracking reaction. However, certain drawbacks such as catalyst cost, deactivation, and regeneration remain unsolved in this process. In this study, we focused on potential Malaysian dolomite (Perlis) as the source of catalysts for palm frond gasification. The influences of mechanochemical treatment in three different media (air, ethanol, and water) on the catalytic activity of the material were analyzed. Important changes in the properties of the dolomite along with the high catalytic performance were noted as the results of the treatment. Notable changes in the dolomite structure and porosity were observed because of the impact of the treatment. Increment in the surface area of the catalysts boosts the H2 production and catalytic activity of dolomite. Moreover, substantial CO2 reduction was also observed during reaction as a result of the absorption capacity of treated dolomite. Thus, through mechanochemical treatment, the property of Malaysian dolomite is being greatly altered, which really suits as a potential catalyst for gasification. John Wiley & Sons 2014-06-25 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/34560/1/Modification%20of%20Malaysian%20dolomite%20using%20mechanochemical%20treatment%20via%20different%20media%20for%20oil%20palm%20fronds%20gasification.pdf Yap, Taufiq Yun Hin and Abdul Rahim, Nur Faizal and Seenivasagam, Sivasangar and Hussein, Mohd Zobir and Ahmad, Aishah (2014) Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification. International Journal of Energy Research, 38 (8). pp. 1008-1015. ISSN 0363-907X; ESSN: 1099-114X http://onlinelibrary.wiley.com/doi/10.1002/er.3118/abstract 10.1002/er.3118
spellingShingle Yap, Taufiq Yun Hin
Abdul Rahim, Nur Faizal
Seenivasagam, Sivasangar
Hussein, Mohd Zobir
Ahmad, Aishah
Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification
title Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification
title_full Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification
title_fullStr Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification
title_full_unstemmed Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification
title_short Modification of Malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification
title_sort modification of malaysian dolomite using mechanochemical treatment via different media for oil palm fronds gasification
url http://psasir.upm.edu.my/id/eprint/34560/
http://psasir.upm.edu.my/id/eprint/34560/
http://psasir.upm.edu.my/id/eprint/34560/
http://psasir.upm.edu.my/id/eprint/34560/1/Modification%20of%20Malaysian%20dolomite%20using%20mechanochemical%20treatment%20via%20different%20media%20for%20oil%20palm%20fronds%20gasification.pdf