A Kinetic Study on the Esterification of Palmitic Acid in Methanol

The esterification of palmitic acid in excess methanol using thionyl chloride as catalyst has been investigated. It was found that SOCl2 behaved as a good esterification catalyst. The methyl palmitate product obtained has been analysed and characterized using gas chromatography and gas chromatograp...

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Main Authors: Kamaruddin, Rose aini, Mohammad Nordin, Nor Asyikin, Buang, Nor Aziah, Ahmad, Saliza
Format: Article
Language:English
English
Published: Universiti Putra Malaysia Press 1998
Online Access:http://psasir.upm.edu.my/id/eprint/3410/
http://psasir.upm.edu.my/id/eprint/3410/1/A_Kinetic_Study_on_the_Esterification_of_Palmitic.pdf
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author Kamaruddin, Rose aini
Mohammad Nordin, Nor Asyikin
Buang, Nor Aziah
Ahmad, Saliza
author_facet Kamaruddin, Rose aini
Mohammad Nordin, Nor Asyikin
Buang, Nor Aziah
Ahmad, Saliza
author_sort Kamaruddin, Rose aini
building UPM Institutional Repository
collection Online Access
description The esterification of palmitic acid in excess methanol using thionyl chloride as catalyst has been investigated. It was found that SOCl2 behaved as a good esterification catalyst. The methyl palmitate product obtained has been analysed and characterized using gas chromatography and gas chromatography-mass spectrometry. Optimization studies to determine' the weight percent of catalyst to acid, temperature and time to produce maximum yield of product have also been carried out. The optimum conditions were found to be 0.3% weight of catalyst to acid, 80°C and 2 hours. Subsequently, the rate constants at various temperatures and activation energy of the system were calculated.
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institution Universiti Putra Malaysia
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language English
English
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publishDate 1998
publisher Universiti Putra Malaysia Press
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spelling upm-34102013-05-27T07:08:17Z http://psasir.upm.edu.my/id/eprint/3410/ A Kinetic Study on the Esterification of Palmitic Acid in Methanol Kamaruddin, Rose aini Mohammad Nordin, Nor Asyikin Buang, Nor Aziah Ahmad, Saliza The esterification of palmitic acid in excess methanol using thionyl chloride as catalyst has been investigated. It was found that SOCl2 behaved as a good esterification catalyst. The methyl palmitate product obtained has been analysed and characterized using gas chromatography and gas chromatography-mass spectrometry. Optimization studies to determine' the weight percent of catalyst to acid, temperature and time to produce maximum yield of product have also been carried out. The optimum conditions were found to be 0.3% weight of catalyst to acid, 80°C and 2 hours. Subsequently, the rate constants at various temperatures and activation energy of the system were calculated. Universiti Putra Malaysia Press 1998 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/3410/1/A_Kinetic_Study_on_the_Esterification_of_Palmitic.pdf Kamaruddin, Rose aini and Mohammad Nordin, Nor Asyikin and Buang, Nor Aziah and Ahmad, Saliza (1998) A Kinetic Study on the Esterification of Palmitic Acid in Methanol. Pertanika Journal of Science & Technology, 6 (1). pp. 71-79. ISSN 0128-7680 English
spellingShingle Kamaruddin, Rose aini
Mohammad Nordin, Nor Asyikin
Buang, Nor Aziah
Ahmad, Saliza
A Kinetic Study on the Esterification of Palmitic Acid in Methanol
title A Kinetic Study on the Esterification of Palmitic Acid in Methanol
title_full A Kinetic Study on the Esterification of Palmitic Acid in Methanol
title_fullStr A Kinetic Study on the Esterification of Palmitic Acid in Methanol
title_full_unstemmed A Kinetic Study on the Esterification of Palmitic Acid in Methanol
title_short A Kinetic Study on the Esterification of Palmitic Acid in Methanol
title_sort kinetic study on the esterification of palmitic acid in methanol
url http://psasir.upm.edu.my/id/eprint/3410/
http://psasir.upm.edu.my/id/eprint/3410/1/A_Kinetic_Study_on_the_Esterification_of_Palmitic.pdf