Bio-based crotonic acid production

The invention provides method for producing high selectivity trans-crotonic acid from bio-based resource wherein the steps comprise of treatment of poly(3-hydroxbutyrate) (PHB) biomass with mild alkali; and thermal degradation of the PHB biomass. Crotonic acid, a dehydrated monomer of PHB, can be ob...

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Main Authors: Ariffin, Hidayah, Farid, Nur Falia Shazana Manja, Zakaria @ Mamat, Mohd Rahimi, Hassan, Mohd Ali
Format: Patent
Published: 2014
Online Access:http://psasir.upm.edu.my/id/eprint/33967/
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author Ariffin, Hidayah
Farid, Nur Falia Shazana Manja
Zakaria @ Mamat, Mohd Rahimi
Hassan, Mohd Ali
author_facet Ariffin, Hidayah
Farid, Nur Falia Shazana Manja
Zakaria @ Mamat, Mohd Rahimi
Hassan, Mohd Ali
author_sort Ariffin, Hidayah
building UPM Institutional Repository
collection Online Access
description The invention provides method for producing high selectivity trans-crotonic acid from bio-based resource wherein the steps comprise of treatment of poly(3-hydroxbutyrate) (PHB) biomass with mild alkali; and thermal degradation of the PHB biomass. Crotonic acid, a dehydrated monomer of PHB, can be obtained by thermal degradation under controlled temperature and retention time. Currently, crotonic acid is chemically synthesized via non-renewable resources. As an alternative, it can be produced biologically within cells in its hydrated polymer PHB form, and subsequently pyrolyzed to obtain crotonic acid.The invention also provides a method of producing crotonic acid by thermal degradation of wet or dry PHB biomass in the presence of magnesium compound. The present invention provides a method for treating PHB Biomass with low concentration of sodium hydroxide with molarity in between 0.05-0.1M.
first_indexed 2025-11-15T09:21:52Z
format Patent
id upm-33967
institution Universiti Putra Malaysia
institution_category Local University
last_indexed 2025-11-15T09:21:52Z
publishDate 2014
recordtype eprints
repository_type Digital Repository
spelling upm-339672016-09-08T02:32:02Z http://psasir.upm.edu.my/id/eprint/33967/ Bio-based crotonic acid production Ariffin, Hidayah Farid, Nur Falia Shazana Manja Zakaria @ Mamat, Mohd Rahimi Hassan, Mohd Ali The invention provides method for producing high selectivity trans-crotonic acid from bio-based resource wherein the steps comprise of treatment of poly(3-hydroxbutyrate) (PHB) biomass with mild alkali; and thermal degradation of the PHB biomass. Crotonic acid, a dehydrated monomer of PHB, can be obtained by thermal degradation under controlled temperature and retention time. Currently, crotonic acid is chemically synthesized via non-renewable resources. As an alternative, it can be produced biologically within cells in its hydrated polymer PHB form, and subsequently pyrolyzed to obtain crotonic acid.The invention also provides a method of producing crotonic acid by thermal degradation of wet or dry PHB biomass in the presence of magnesium compound. The present invention provides a method for treating PHB Biomass with low concentration of sodium hydroxide with molarity in between 0.05-0.1M. 2014-09-12 Patent NonPeerReviewed Hidayah Ariffin (2014) Bio-based crotonic acid production. PI2014702609.
spellingShingle Ariffin, Hidayah
Farid, Nur Falia Shazana Manja
Zakaria @ Mamat, Mohd Rahimi
Hassan, Mohd Ali
Bio-based crotonic acid production
title Bio-based crotonic acid production
title_full Bio-based crotonic acid production
title_fullStr Bio-based crotonic acid production
title_full_unstemmed Bio-based crotonic acid production
title_short Bio-based crotonic acid production
title_sort bio-based crotonic acid production
url http://psasir.upm.edu.my/id/eprint/33967/