[1,5] and [1,2] acetyl shifts in Diels-Alder adducts of 2-acetyl-6-methyl-l,4-benzoquinone
Treatment of the Diels-Alder adduct 4a-acetyl-4a, 5, 8, 8a-tetrahydro-3-methyl-I, 4 naphthoquinone with pyridine-methanol or acetic anhydride leads to a [I, 5J acetyl shift to the 3-position which can be followed by a [1,2J acetyl shift to the 2-position (adduct numbering).
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
The Royal Society of Chemistry
1981
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| Online Access: | http://psasir.upm.edu.my/id/eprint/33816/ http://psasir.upm.edu.my/id/eprint/33816/1/33816%20acetyl%20shifts.pdf |
| _version_ | 1848847603211436032 |
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| author | Ahmad, Faujan Bruce, J. Malcolm Khalafy, Jabbar Sabetian, Khojasteh |
| author_facet | Ahmad, Faujan Bruce, J. Malcolm Khalafy, Jabbar Sabetian, Khojasteh |
| author_sort | Ahmad, Faujan |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Treatment of the Diels-Alder adduct 4a-acetyl-4a, 5, 8, 8a-tetrahydro-3-methyl-I, 4 naphthoquinone with pyridine-methanol or acetic anhydride leads to a [I, 5J acetyl shift to the 3-position which can be followed by a [1,2J acetyl shift to the 2-position (adduct numbering). |
| first_indexed | 2025-11-15T09:21:14Z |
| format | Article |
| id | upm-33816 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T09:21:14Z |
| publishDate | 1981 |
| publisher | The Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-338162015-04-13T02:54:24Z http://psasir.upm.edu.my/id/eprint/33816/ [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of 2-acetyl-6-methyl-l,4-benzoquinone Ahmad, Faujan Bruce, J. Malcolm Khalafy, Jabbar Sabetian, Khojasteh Treatment of the Diels-Alder adduct 4a-acetyl-4a, 5, 8, 8a-tetrahydro-3-methyl-I, 4 naphthoquinone with pyridine-methanol or acetic anhydride leads to a [I, 5J acetyl shift to the 3-position which can be followed by a [1,2J acetyl shift to the 2-position (adduct numbering). The Royal Society of Chemistry 1981 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/33816/1/33816%20acetyl%20shifts.pdf Ahmad, Faujan and Bruce, J. Malcolm and Khalafy, Jabbar and Sabetian, Khojasteh (1981) [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of 2-acetyl-6-methyl-l,4-benzoquinone. Journal of the Chemical Society, Chemical Communications, 4. pp. 169-171. ISSN 0022-4936 http://pubs.rsc.org/en/content/articlelanding/1981/c3/c39810000169#!divAbstract 10.1039/C39810000169 |
| spellingShingle | Ahmad, Faujan Bruce, J. Malcolm Khalafy, Jabbar Sabetian, Khojasteh [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of 2-acetyl-6-methyl-l,4-benzoquinone |
| title | [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of
2-acetyl-6-methyl-l,4-benzoquinone |
| title_full | [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of
2-acetyl-6-methyl-l,4-benzoquinone |
| title_fullStr | [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of
2-acetyl-6-methyl-l,4-benzoquinone |
| title_full_unstemmed | [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of
2-acetyl-6-methyl-l,4-benzoquinone |
| title_short | [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of
2-acetyl-6-methyl-l,4-benzoquinone |
| title_sort | [1,5] and [1,2] acetyl shifts in diels-alder adducts of
2-acetyl-6-methyl-l,4-benzoquinone |
| url | http://psasir.upm.edu.my/id/eprint/33816/ http://psasir.upm.edu.my/id/eprint/33816/ http://psasir.upm.edu.my/id/eprint/33816/ http://psasir.upm.edu.my/id/eprint/33816/1/33816%20acetyl%20shifts.pdf |