Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System

A preliminary investigation was carried out on the phase equilibria in the three component systems, water/sodium caprylate/octanoic acid, water/sodium caprylate and sodium dodecyl sulphate (l:1) / octanoic acid at 30°C. The phases were separated by repeated centrifugation. The birefringence was ob...

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Main Authors: Suhaimi, Hamdan, Kassim, Anuar, Che Rose, Laili
Format: Article
Language:English
English
Published: Universiti Putra Malaysia Press 1993
Online Access:http://psasir.upm.edu.my/id/eprint/3088/
http://psasir.upm.edu.my/id/eprint/3088/1/Phase_Equilibria_of_a_Mixed_Alkali_Soap.pdf
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author Suhaimi, Hamdan
Kassim, Anuar
Che Rose, Laili
author_facet Suhaimi, Hamdan
Kassim, Anuar
Che Rose, Laili
author_sort Suhaimi, Hamdan
building UPM Institutional Repository
collection Online Access
description A preliminary investigation was carried out on the phase equilibria in the three component systems, water/sodium caprylate/octanoic acid, water/sodium caprylate and sodium dodecyl sulphate (l:1) / octanoic acid at 30°C. The phases were separated by repeated centrifugation. The birefringence was observed under cross-polarisers and their consistency, texture and optical pattern were examined under the polarizing microscope. On the basis of the results obtained, a phase diagram was drawn that includes two phases of isotropic solution and two mesophases. Results also showed a decreased amount of octanoic acid utilized in obtaining the lamellar liquid crystal phase. The critical micelle concentration was also reduced for the mixed surfactant system
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publishDate 1993
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spelling upm-30882013-05-27T07:05:38Z http://psasir.upm.edu.my/id/eprint/3088/ Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System Suhaimi, Hamdan Kassim, Anuar Che Rose, Laili A preliminary investigation was carried out on the phase equilibria in the three component systems, water/sodium caprylate/octanoic acid, water/sodium caprylate and sodium dodecyl sulphate (l:1) / octanoic acid at 30°C. The phases were separated by repeated centrifugation. The birefringence was observed under cross-polarisers and their consistency, texture and optical pattern were examined under the polarizing microscope. On the basis of the results obtained, a phase diagram was drawn that includes two phases of isotropic solution and two mesophases. Results also showed a decreased amount of octanoic acid utilized in obtaining the lamellar liquid crystal phase. The critical micelle concentration was also reduced for the mixed surfactant system Universiti Putra Malaysia Press 1993 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/3088/1/Phase_Equilibria_of_a_Mixed_Alkali_Soap.pdf Suhaimi, Hamdan and Kassim, Anuar and Che Rose, Laili (1993) Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System. Pertanika Journal of Science & Technology, 1 (1). pp. 1-10. ISSN 0128-7680 English
spellingShingle Suhaimi, Hamdan
Kassim, Anuar
Che Rose, Laili
Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System
title Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System
title_full Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System
title_fullStr Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System
title_full_unstemmed Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System
title_short Phase Equilibria of a Mixed Alkali Soap/ Carboxylic Acid/Water System
title_sort phase equilibria of a mixed alkali soap/ carboxylic acid/water system
url http://psasir.upm.edu.my/id/eprint/3088/
http://psasir.upm.edu.my/id/eprint/3088/1/Phase_Equilibria_of_a_Mixed_Alkali_Soap.pdf