FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers

A biodegradable composite (PLA/KBF blends) was prepared using melt blending technique in a brabender mixer and characterized with FTIR and TGA analyzer. Five percent of triacetin and glycerol contents were used as plasticizers to plasticise PLA matrix. KBF was treated with 4% NaOH solution, whil...

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Main Authors: Othman, Maizatulnisa, Ibrahim, Nor Azowa, Wan Yunus, Wan Md. Zin, Abdan, Khalina, Khalid, Khalisanni
Format: Article
Language:English
Published: Universiti Putra Malaysia Press 2013
Online Access:http://psasir.upm.edu.my/id/eprint/30411/
http://psasir.upm.edu.my/id/eprint/30411/1/31.%20FTIR%20and%20TGA%20Analysis%20of%20Biodegradable%20Poly.pdf
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author Othman, Maizatulnisa
Ibrahim, Nor Azowa
Wan Yunus, Wan Md. Zin
Abdan, Khalina
Khalid, Khalisanni
author_facet Othman, Maizatulnisa
Ibrahim, Nor Azowa
Wan Yunus, Wan Md. Zin
Abdan, Khalina
Khalid, Khalisanni
author_sort Othman, Maizatulnisa
building UPM Institutional Repository
collection Online Access
description A biodegradable composite (PLA/KBF blends) was prepared using melt blending technique in a brabender mixer and characterized with FTIR and TGA analyzer. Five percent of triacetin and glycerol contents were used as plasticizers to plasticise PLA matrix. KBF was treated with 4% NaOH solution, while 30 wt% of fibre loading was used constantly for all the composite samples. From the FTIR analysis, the additions of triacetin and glycerol to PLA composites did not produce any significant difference, and there were no chemical changes in both the plasticized PLA with the treated and untreated KBF, respectively. Observation done on the TGA analysis revealed that both plasticizers did improve the thermal stability of the composites, and this might be due to the modification on the fibre surfaces, which further led to the delay in the degradation of the PLA matrix and to significant stabilization effect.
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spelling upm-304112015-11-04T07:23:05Z http://psasir.upm.edu.my/id/eprint/30411/ FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers Othman, Maizatulnisa Ibrahim, Nor Azowa Wan Yunus, Wan Md. Zin Abdan, Khalina Khalid, Khalisanni A biodegradable composite (PLA/KBF blends) was prepared using melt blending technique in a brabender mixer and characterized with FTIR and TGA analyzer. Five percent of triacetin and glycerol contents were used as plasticizers to plasticise PLA matrix. KBF was treated with 4% NaOH solution, while 30 wt% of fibre loading was used constantly for all the composite samples. From the FTIR analysis, the additions of triacetin and glycerol to PLA composites did not produce any significant difference, and there were no chemical changes in both the plasticized PLA with the treated and untreated KBF, respectively. Observation done on the TGA analysis revealed that both plasticizers did improve the thermal stability of the composites, and this might be due to the modification on the fibre surfaces, which further led to the delay in the degradation of the PLA matrix and to significant stabilization effect. Universiti Putra Malaysia Press 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30411/1/31.%20FTIR%20and%20TGA%20Analysis%20of%20Biodegradable%20Poly.pdf Othman, Maizatulnisa and Ibrahim, Nor Azowa and Wan Yunus, Wan Md. Zin and Abdan, Khalina and Khalid, Khalisanni (2013) FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers. Pertanika Journal of Science & Technology, 21 (1). pp. 151-160. ISSN 0128-7680; ESSN: 2231-8526 http://pertanika.upm.edu.my/Pertanika%20PAPERS/JST%20Vol.%2021%20(1)%20Jan.%202013/14.%20Page%20151-160.pdf
spellingShingle Othman, Maizatulnisa
Ibrahim, Nor Azowa
Wan Yunus, Wan Md. Zin
Abdan, Khalina
Khalid, Khalisanni
FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers
title FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers
title_full FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers
title_fullStr FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers
title_full_unstemmed FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers
title_short FTIR and TGA analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers
title_sort ftir and tga analysis of biodegradable poly(lactic acid)/ treated kenaf bast fibre: effect of plasticizers
url http://psasir.upm.edu.my/id/eprint/30411/
http://psasir.upm.edu.my/id/eprint/30411/
http://psasir.upm.edu.my/id/eprint/30411/1/31.%20FTIR%20and%20TGA%20Analysis%20of%20Biodegradable%20Poly.pdf