Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study

ZnO/γ-Fe2O3 nanocomposite was synthesized via simple precipitation. The synthesized nanocatalysts underwent heat treatment at 450oC for an hour. The characteristics of the nanocomposite were investigated by XRD, TEM, and BET surface area measurement. Zeta potential analysis was used to examine t...

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Main Authors: Abdullah, Abdul Halim, Lee, Kian Mun, Zainal, Zulkarnain, Hussein, Mohd Zobir
Format: Article
Language:English
Published: Canadian Center of Science and Education 2013
Online Access:http://psasir.upm.edu.my/id/eprint/30391/
http://psasir.upm.edu.my/id/eprint/30391/1/Photodegradation%20of%20chlorophenoxyacetic%20acids%20by%20ZnO.pdf
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author Abdullah, Abdul Halim
Lee, Kian Mun
Zainal, Zulkarnain
Hussein, Mohd Zobir
author_facet Abdullah, Abdul Halim
Lee, Kian Mun
Zainal, Zulkarnain
Hussein, Mohd Zobir
author_sort Abdullah, Abdul Halim
building UPM Institutional Repository
collection Online Access
description ZnO/γ-Fe2O3 nanocomposite was synthesized via simple precipitation. The synthesized nanocatalysts underwent heat treatment at 450oC for an hour. The characteristics of the nanocomposite were investigated by XRD, TEM, and BET surface area measurement. Zeta potential analysis was used to examine the surface charge properties of the nanocatalysts. The synthesized nanocomposite has an average particle size of 11 nm and a surface area of 20 m2 g-1. The potential of ZnO/γ-Fe2O3 as a photocatalyst was evaluated by photodegrading chlorophenoxyacetic acids (PAA, 2,4-D, 2,4,5-T and 4CA). The decomposition of chlorophenoxyacetic acids by ZnO/γ-Fe2O3 followed 4CA > 2,4,5-T ≈ 2,4-D > PAA. The result indicates the applicability of ZnO/γ-Fe2O3 nanocomposite as a photocatalyst in removing organic pollutants in wastewater.
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spelling upm-303912015-09-17T07:31:31Z http://psasir.upm.edu.my/id/eprint/30391/ Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study Abdullah, Abdul Halim Lee, Kian Mun Zainal, Zulkarnain Hussein, Mohd Zobir ZnO/γ-Fe2O3 nanocomposite was synthesized via simple precipitation. The synthesized nanocatalysts underwent heat treatment at 450oC for an hour. The characteristics of the nanocomposite were investigated by XRD, TEM, and BET surface area measurement. Zeta potential analysis was used to examine the surface charge properties of the nanocatalysts. The synthesized nanocomposite has an average particle size of 11 nm and a surface area of 20 m2 g-1. The potential of ZnO/γ-Fe2O3 as a photocatalyst was evaluated by photodegrading chlorophenoxyacetic acids (PAA, 2,4-D, 2,4,5-T and 4CA). The decomposition of chlorophenoxyacetic acids by ZnO/γ-Fe2O3 followed 4CA > 2,4,5-T ≈ 2,4-D > PAA. The result indicates the applicability of ZnO/γ-Fe2O3 nanocomposite as a photocatalyst in removing organic pollutants in wastewater. Canadian Center of Science and Education 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30391/1/Photodegradation%20of%20chlorophenoxyacetic%20acids%20by%20ZnO.pdf Abdullah, Abdul Halim and Lee, Kian Mun and Zainal, Zulkarnain and Hussein, Mohd Zobir (2013) Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study. International Journal of Chemistry, 5 (4). pp. 56-65. ISSN 1916-9698; ESSN: 1916-9701 http://www.ccsenet.org/journal/index.php/ijc/issue/view/895 10.5539/ijc.v5n4p56
spellingShingle Abdullah, Abdul Halim
Lee, Kian Mun
Zainal, Zulkarnain
Hussein, Mohd Zobir
Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study
title Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study
title_full Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study
title_fullStr Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study
title_full_unstemmed Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study
title_short Photodegradation of chlorophenoxyacetic acids by ZnO/y-Fe2O3 nanocatalysts : a comparative study
title_sort photodegradation of chlorophenoxyacetic acids by zno/y-fe2o3 nanocatalysts : a comparative study
url http://psasir.upm.edu.my/id/eprint/30391/
http://psasir.upm.edu.my/id/eprint/30391/
http://psasir.upm.edu.my/id/eprint/30391/
http://psasir.upm.edu.my/id/eprint/30391/1/Photodegradation%20of%20chlorophenoxyacetic%20acids%20by%20ZnO.pdf