Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI)

In this study, fatty amides (FAs) synthesized from palm olein were used to extract and separate Mo(VI) from acidic media. Effects of various parameters upon the separation of Mo(VI) from Co(II), Ni(II), Al(III) and Mn(II), including extractant concentration, metal ion concentration, contact time, di...

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Main Authors: Al-Mulla, Emad A. Jaffar, Ibrahim, Nor Azowa, Shameli, Kamyar, Ahmad @ Ayob, Mansor, Wan Yunus, Wan Md. Zin
Format: Article
Language:English
English
Published: Springer Netherlands 2013
Online Access:http://psasir.upm.edu.my/id/eprint/30336/
http://psasir.upm.edu.my/id/eprint/30336/1/Fatty%20amides%20synthesized%20from%20vegetable%20oil%20as%20extractant%20of%20molybdenum.pdf
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author Al-Mulla, Emad A. Jaffar
Ibrahim, Nor Azowa
Shameli, Kamyar
Ahmad @ Ayob, Mansor
Wan Yunus, Wan Md. Zin
author_facet Al-Mulla, Emad A. Jaffar
Ibrahim, Nor Azowa
Shameli, Kamyar
Ahmad @ Ayob, Mansor
Wan Yunus, Wan Md. Zin
author_sort Al-Mulla, Emad A. Jaffar
building UPM Institutional Repository
collection Online Access
description In this study, fatty amides (FAs) synthesized from palm olein were used to extract and separate Mo(VI) from acidic media. Effects of various parameters upon the separation of Mo(VI) from Co(II), Ni(II), Al(III) and Mn(II), including extractant concentration, metal ion concentration, contact time, diluent, and acidity, were investigated. It was found that Mo(VI) was successfully separated from the above commonly associated metal ions by stripping from the loaded organic phase. Different acidic and alkaline solutions were used. Ammonium hydroxide solution was an optimal. Extraction of Mo(VI) into the organic phase involved the formation of 1:3 complexes. This work presents the development of a low-cost and environmentally friendly extractant to recycle and recover molybdenum.
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English
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publishDate 2013
publisher Springer Netherlands
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spelling upm-303362015-09-10T06:48:49Z http://psasir.upm.edu.my/id/eprint/30336/ Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI) Al-Mulla, Emad A. Jaffar Ibrahim, Nor Azowa Shameli, Kamyar Ahmad @ Ayob, Mansor Wan Yunus, Wan Md. Zin In this study, fatty amides (FAs) synthesized from palm olein were used to extract and separate Mo(VI) from acidic media. Effects of various parameters upon the separation of Mo(VI) from Co(II), Ni(II), Al(III) and Mn(II), including extractant concentration, metal ion concentration, contact time, diluent, and acidity, were investigated. It was found that Mo(VI) was successfully separated from the above commonly associated metal ions by stripping from the loaded organic phase. Different acidic and alkaline solutions were used. Ammonium hydroxide solution was an optimal. Extraction of Mo(VI) into the organic phase involved the formation of 1:3 complexes. This work presents the development of a low-cost and environmentally friendly extractant to recycle and recover molybdenum. Springer Netherlands 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30336/1/Fatty%20amides%20synthesized%20from%20vegetable%20oil%20as%20extractant%20of%20molybdenum.pdf Al-Mulla, Emad A. Jaffar and Ibrahim, Nor Azowa and Shameli, Kamyar and Ahmad @ Ayob, Mansor and Wan Yunus, Wan Md. Zin (2013) Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI). Research on Chemical Intermediates, 39 (3). pp. 1313-1321. ISSN 0922-6168; ESSN: 1568-5675 10.1007/s11164-012-0687-6 English
spellingShingle Al-Mulla, Emad A. Jaffar
Ibrahim, Nor Azowa
Shameli, Kamyar
Ahmad @ Ayob, Mansor
Wan Yunus, Wan Md. Zin
Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI)
title Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI)
title_full Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI)
title_fullStr Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI)
title_full_unstemmed Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI)
title_short Fatty amides synthesized from vegetable oil as extractant of molybdenum(VI)
title_sort fatty amides synthesized from vegetable oil as extractant of molybdenum(vi)
url http://psasir.upm.edu.my/id/eprint/30336/
http://psasir.upm.edu.my/id/eprint/30336/
http://psasir.upm.edu.my/id/eprint/30336/1/Fatty%20amides%20synthesized%20from%20vegetable%20oil%20as%20extractant%20of%20molybdenum.pdf