Spectrofluorimetric determination of arsenic(III) using dansylated peptide

The potential of dansylated peptide in determination of arsenic(III) was investigated. Fluorescence intensity of dansyl-D-Ala-Gly-OH (DAG) was quenched during addition of arsenic(III) in aqueous solution. The fluorescence spectrum of DAG was measured at pH 12 with excitation and emission wavelengths...

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Main Authors: Abdull Manap, Mohd Rashidi, Yusof, Nor Azah, Mohd Nor, Siti Mariam, Ahmad, Faujan
Format: Article
Language:English
English
Published: Chemic Publishing Company 2013
Online Access:http://psasir.upm.edu.my/id/eprint/30162/
http://psasir.upm.edu.my/id/eprint/30162/1/Spectrofluorimetric%20determination%20of%20arsenic.pdf
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author Abdull Manap, Mohd Rashidi
Yusof, Nor Azah
Mohd Nor, Siti Mariam
Ahmad, Faujan
author_facet Abdull Manap, Mohd Rashidi
Yusof, Nor Azah
Mohd Nor, Siti Mariam
Ahmad, Faujan
author_sort Abdull Manap, Mohd Rashidi
building UPM Institutional Repository
collection Online Access
description The potential of dansylated peptide in determination of arsenic(III) was investigated. Fluorescence intensity of dansyl-D-Ala-Gly-OH (DAG) was quenched during addition of arsenic(III) in aqueous solution. The fluorescence spectrum of DAG was measured at pH 12 with excitation and emission wavelengths of 331 nm and 524 nm. Limit of detection of arsenic(III) by DAG is 0.15 μM. The presence of foreign ions at 1:1 molar ratio of arsenic(III)-interfering ions did not have significant effect on determination of arsenic(III). The developed detection method was also applied on analysis of electroplating waste samples.
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institution Universiti Putra Malaysia
institution_category Local University
language English
English
last_indexed 2025-11-15T09:05:17Z
publishDate 2013
publisher Chemic Publishing Company
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spelling upm-301622015-09-21T00:16:31Z http://psasir.upm.edu.my/id/eprint/30162/ Spectrofluorimetric determination of arsenic(III) using dansylated peptide Abdull Manap, Mohd Rashidi Yusof, Nor Azah Mohd Nor, Siti Mariam Ahmad, Faujan The potential of dansylated peptide in determination of arsenic(III) was investigated. Fluorescence intensity of dansyl-D-Ala-Gly-OH (DAG) was quenched during addition of arsenic(III) in aqueous solution. The fluorescence spectrum of DAG was measured at pH 12 with excitation and emission wavelengths of 331 nm and 524 nm. Limit of detection of arsenic(III) by DAG is 0.15 μM. The presence of foreign ions at 1:1 molar ratio of arsenic(III)-interfering ions did not have significant effect on determination of arsenic(III). The developed detection method was also applied on analysis of electroplating waste samples. Chemic Publishing Company 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30162/1/Spectrofluorimetric%20determination%20of%20arsenic.pdf Abdull Manap, Mohd Rashidi and Yusof, Nor Azah and Mohd Nor, Siti Mariam and Ahmad, Faujan (2013) Spectrofluorimetric determination of arsenic(III) using dansylated peptide. Asian Journal of Chemistry, 25 (8). pp. 4195-4198. ISSN 0970-7077 English
spellingShingle Abdull Manap, Mohd Rashidi
Yusof, Nor Azah
Mohd Nor, Siti Mariam
Ahmad, Faujan
Spectrofluorimetric determination of arsenic(III) using dansylated peptide
title Spectrofluorimetric determination of arsenic(III) using dansylated peptide
title_full Spectrofluorimetric determination of arsenic(III) using dansylated peptide
title_fullStr Spectrofluorimetric determination of arsenic(III) using dansylated peptide
title_full_unstemmed Spectrofluorimetric determination of arsenic(III) using dansylated peptide
title_short Spectrofluorimetric determination of arsenic(III) using dansylated peptide
title_sort spectrofluorimetric determination of arsenic(iii) using dansylated peptide
url http://psasir.upm.edu.my/id/eprint/30162/
http://psasir.upm.edu.my/id/eprint/30162/1/Spectrofluorimetric%20determination%20of%20arsenic.pdf