Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles

Nickel oxide nanoparticles (NiO NPs) were synthesised using a sol–gel method in a gelatinous medium. Gelatine was used as a size-limiting polymerisation agent for the growth of NiO NPs. X-ray diffraction (XRD) analysis revealed that increasing the calcination temperature increased the crystallite si...

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Main Authors: Jahromi, Siamak Pilban, Huang, Nay Ming, Muhamad, Muhamad Rasat, Lim, Hong Ngee
Format: Article
Language:English
Published: Elsevier 2013
Online Access:http://psasir.upm.edu.my/id/eprint/29988/
http://psasir.upm.edu.my/id/eprint/29988/1/Green%20gelatine.pdf
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author Jahromi, Siamak Pilban
Huang, Nay Ming
Muhamad, Muhamad Rasat
Lim, Hong Ngee
author_facet Jahromi, Siamak Pilban
Huang, Nay Ming
Muhamad, Muhamad Rasat
Lim, Hong Ngee
author_sort Jahromi, Siamak Pilban
building UPM Institutional Repository
collection Online Access
description Nickel oxide nanoparticles (NiO NPs) were synthesised using a sol–gel method in a gelatinous medium. Gelatine was used as a size-limiting polymerisation agent for the growth of NiO NPs. X-ray diffraction (XRD) analysis revealed that increasing the calcination temperature increased the crystallite size and decreased the size of the lattice constant. The size-strain plot method (SSP) was used to measure the individual contribution of grain sizes and micro strain on the peak broadening of NiO NPs. Transmission electron microscopy (TEM) showed the ultrasmall size of the NiO NPs with a narrow size distribution(10±0.2 nm). The band gap value of NiO NPs was calculated using ultraviolet–visible (UV–Vis) spectroscopy and decreased with increased calcination temperature.
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spelling upm-299882016-03-21T09:26:51Z http://psasir.upm.edu.my/id/eprint/29988/ Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles Jahromi, Siamak Pilban Huang, Nay Ming Muhamad, Muhamad Rasat Lim, Hong Ngee Nickel oxide nanoparticles (NiO NPs) were synthesised using a sol–gel method in a gelatinous medium. Gelatine was used as a size-limiting polymerisation agent for the growth of NiO NPs. X-ray diffraction (XRD) analysis revealed that increasing the calcination temperature increased the crystallite size and decreased the size of the lattice constant. The size-strain plot method (SSP) was used to measure the individual contribution of grain sizes and micro strain on the peak broadening of NiO NPs. Transmission electron microscopy (TEM) showed the ultrasmall size of the NiO NPs with a narrow size distribution(10±0.2 nm). The band gap value of NiO NPs was calculated using ultraviolet–visible (UV–Vis) spectroscopy and decreased with increased calcination temperature. Elsevier 2013-05 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/29988/1/Green%20gelatine.pdf Jahromi, Siamak Pilban and Huang, Nay Ming and Muhamad, Muhamad Rasat and Lim, Hong Ngee (2013) Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles. Ceramics International, 39 (4). pp. 3909-3914. ISSN 0272-8842; ESSN: 1873-3956 10.1016/j.ceramint.2012.10.237
spellingShingle Jahromi, Siamak Pilban
Huang, Nay Ming
Muhamad, Muhamad Rasat
Lim, Hong Ngee
Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles
title Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles
title_full Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles
title_fullStr Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles
title_full_unstemmed Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles
title_short Green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles
title_sort green gelatine-assisted sol–gel synthesis of ultrasmall nickel oxide nanoparticles
url http://psasir.upm.edu.my/id/eprint/29988/
http://psasir.upm.edu.my/id/eprint/29988/
http://psasir.upm.edu.my/id/eprint/29988/1/Green%20gelatine.pdf