One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature

A stable aqueous suspension of functional graphene oxide/silver nanocomposite (FGO/Ag) was prepared in an alkaline medium by a simple room temperature stirring method. Functional graphene oxide (FGO) served as substrate, reducing agent and stabilizer for the silver nanoparticles (Ag-NPs). The pH of...

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Main Authors: Vijay Kumar, S., Huang, Nay Ming, Lim, Hong Ngee, Abdul Rahman, Marlinda, Harrison, I., Chia, Chin Hua
Format: Article
Language:English
Published: Elsevier 2013
Online Access:http://psasir.upm.edu.my/id/eprint/29985/
http://psasir.upm.edu.my/id/eprint/29985/1/One%20step%20size%20controlled%20synthesis%20of%20functional%20graphene%20oxide%20silver%20nanocomposites%20at%20room%20temperature..pdf
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author Vijay Kumar, S.
Huang, Nay Ming
Lim, Hong Ngee
Abdul Rahman, Marlinda
Harrison, I.
Chia, Chin Hua
author_facet Vijay Kumar, S.
Huang, Nay Ming
Lim, Hong Ngee
Abdul Rahman, Marlinda
Harrison, I.
Chia, Chin Hua
author_sort Vijay Kumar, S.
building UPM Institutional Repository
collection Online Access
description A stable aqueous suspension of functional graphene oxide/silver nanocomposite (FGO/Ag) was prepared in an alkaline medium by a simple room temperature stirring method. Functional graphene oxide (FGO) served as substrate, reducing agent and stabilizer for the silver nanoparticles (Ag-NPs). The pH of the solution played a prominent role in the formation of the Ag-NPs. The morphology of the nanoparticles (NPs) could be controlled by adjusting the pH between 9.51 and 12.62 by adding NaOH solution. The aqueous stability of the nanocomposites was greatly improved by the attached functional groups. UV-visible spectroscopy, transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM) images suggested the formation of spherical, Ag-NPs with a narrow size distribution at pH 11.40. The nanocomposites showed high bactericidal activity against Escherichia coli bacteria and also enhancement in Raman intensity due to surface enhanced Raman scattering (SERS), which was found to be dependent on the size distribution of the Ag-NPs. This work provides a simple, scalable and environmentally friendly approach to the preparation of a FGO/Ag nanocomposite with promising antibacterial and SERS properties.
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spelling upm-299852016-03-03T13:51:40Z http://psasir.upm.edu.my/id/eprint/29985/ One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature Vijay Kumar, S. Huang, Nay Ming Lim, Hong Ngee Abdul Rahman, Marlinda Harrison, I. Chia, Chin Hua A stable aqueous suspension of functional graphene oxide/silver nanocomposite (FGO/Ag) was prepared in an alkaline medium by a simple room temperature stirring method. Functional graphene oxide (FGO) served as substrate, reducing agent and stabilizer for the silver nanoparticles (Ag-NPs). The pH of the solution played a prominent role in the formation of the Ag-NPs. The morphology of the nanoparticles (NPs) could be controlled by adjusting the pH between 9.51 and 12.62 by adding NaOH solution. The aqueous stability of the nanocomposites was greatly improved by the attached functional groups. UV-visible spectroscopy, transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM) images suggested the formation of spherical, Ag-NPs with a narrow size distribution at pH 11.40. The nanocomposites showed high bactericidal activity against Escherichia coli bacteria and also enhancement in Raman intensity due to surface enhanced Raman scattering (SERS), which was found to be dependent on the size distribution of the Ag-NPs. This work provides a simple, scalable and environmentally friendly approach to the preparation of a FGO/Ag nanocomposite with promising antibacterial and SERS properties. Elsevier 2013-03-01 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/29985/1/One%20step%20size%20controlled%20synthesis%20of%20functional%20graphene%20oxide%20silver%20nanocomposites%20at%20room%20temperature..pdf Vijay Kumar, S. and Huang, Nay Ming and Lim, Hong Ngee and Abdul Rahman, Marlinda and Harrison, I. and Chia, Chin Hua (2013) One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature. Chemical Engineering Journal, 219. pp. 217-224. ISSN 1385-8947; ESSN: 1873-3212 10.1016/j.cej.2012.09.063
spellingShingle Vijay Kumar, S.
Huang, Nay Ming
Lim, Hong Ngee
Abdul Rahman, Marlinda
Harrison, I.
Chia, Chin Hua
One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature
title One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature
title_full One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature
title_fullStr One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature
title_full_unstemmed One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature
title_short One-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature
title_sort one-step size-controlled synthesis of functional graphene oxide/silver nanocomposites at room temperature
url http://psasir.upm.edu.my/id/eprint/29985/
http://psasir.upm.edu.my/id/eprint/29985/
http://psasir.upm.edu.my/id/eprint/29985/1/One%20step%20size%20controlled%20synthesis%20of%20functional%20graphene%20oxide%20silver%20nanocomposites%20at%20room%20temperature..pdf