Short-term field decomposition of pineapple stump biochar in tropical peat soil.

The transformation of biochar on tropical peat is yet to be studied as all previous studies have been conducted on mineral or forest soils. The objectives of this study were to investigate the physical and chemical changes experienced by pineapple stump biochar (PSB) in tropical peat and to determin...

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Main Authors: Cheah, P. M., Mohd Hanif, Ahmad Husni, Abd. Wahid, Samsuri, Abdullah, Luqman Chuah
Format: Article
Language:English
English
Published: Malaysian Society of Soil Science 2013
Online Access:http://psasir.upm.edu.my/id/eprint/29441/
http://psasir.upm.edu.my/id/eprint/29441/1/Short.pdf
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author Cheah, P. M.
Mohd Hanif, Ahmad Husni
Abd. Wahid, Samsuri
Abdullah, Luqman Chuah
author_facet Cheah, P. M.
Mohd Hanif, Ahmad Husni
Abd. Wahid, Samsuri
Abdullah, Luqman Chuah
author_sort Cheah, P. M.
building UPM Institutional Repository
collection Online Access
description The transformation of biochar on tropical peat is yet to be studied as all previous studies have been conducted on mineral or forest soils. The objectives of this study were to investigate the physical and chemical changes experienced by pineapple stump biochar (PSB) in tropical peat and to determine the short-term decomposition model of PSB in a C-rich environment. Elemental composition was determined using CHNS-O analyzer and surface area with Brunauer-Emmett Teller (BET) method. Surface chemistry and structural study were conducted with Fourier Transform Infrared (FTIR) spectroscopy and 13C solid state Nuclear Magnetic Resonance (NMR) spectroscopy, respectively. The PSB short-term decomposition was conducted with a litter bag study and best fitted into the hyperbolic decay model compared to exponential decay model because no significant mass loss was detected after 4 months. The stagnant phase was probably due to interaction with metals from peat. Redox reaction was prominent on the surface and structural chemistry. Surface oxidation of PSB produced more O-functionalities (hydroxyl, carboxylic and phenolic) and achieved chemical recalcitrance after 12 months. The carbon structure was reduced or saturated causing a decrease in electronegativity. Further PSB decomposition probably depends on biotic decomposition.
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spelling upm-294412015-09-15T01:36:30Z http://psasir.upm.edu.my/id/eprint/29441/ Short-term field decomposition of pineapple stump biochar in tropical peat soil. Cheah, P. M. Mohd Hanif, Ahmad Husni Abd. Wahid, Samsuri Abdullah, Luqman Chuah The transformation of biochar on tropical peat is yet to be studied as all previous studies have been conducted on mineral or forest soils. The objectives of this study were to investigate the physical and chemical changes experienced by pineapple stump biochar (PSB) in tropical peat and to determine the short-term decomposition model of PSB in a C-rich environment. Elemental composition was determined using CHNS-O analyzer and surface area with Brunauer-Emmett Teller (BET) method. Surface chemistry and structural study were conducted with Fourier Transform Infrared (FTIR) spectroscopy and 13C solid state Nuclear Magnetic Resonance (NMR) spectroscopy, respectively. The PSB short-term decomposition was conducted with a litter bag study and best fitted into the hyperbolic decay model compared to exponential decay model because no significant mass loss was detected after 4 months. The stagnant phase was probably due to interaction with metals from peat. Redox reaction was prominent on the surface and structural chemistry. Surface oxidation of PSB produced more O-functionalities (hydroxyl, carboxylic and phenolic) and achieved chemical recalcitrance after 12 months. The carbon structure was reduced or saturated causing a decrease in electronegativity. Further PSB decomposition probably depends on biotic decomposition. Malaysian Society of Soil Science 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/29441/1/Short.pdf Cheah, P. M. and Mohd Hanif, Ahmad Husni and Abd. Wahid, Samsuri and Abdullah, Luqman Chuah (2013) Short-term field decomposition of pineapple stump biochar in tropical peat soil. Malaysian Journal of Soil Science, 17. pp. 85-97. ISSN 1394-7990 http://www.msss.com.my/mjss/abs17.html English
spellingShingle Cheah, P. M.
Mohd Hanif, Ahmad Husni
Abd. Wahid, Samsuri
Abdullah, Luqman Chuah
Short-term field decomposition of pineapple stump biochar in tropical peat soil.
title Short-term field decomposition of pineapple stump biochar in tropical peat soil.
title_full Short-term field decomposition of pineapple stump biochar in tropical peat soil.
title_fullStr Short-term field decomposition of pineapple stump biochar in tropical peat soil.
title_full_unstemmed Short-term field decomposition of pineapple stump biochar in tropical peat soil.
title_short Short-term field decomposition of pineapple stump biochar in tropical peat soil.
title_sort short-term field decomposition of pineapple stump biochar in tropical peat soil.
url http://psasir.upm.edu.my/id/eprint/29441/
http://psasir.upm.edu.my/id/eprint/29441/
http://psasir.upm.edu.my/id/eprint/29441/1/Short.pdf