Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite

Degradation of polypropylene (PP) composites at elevated temperature for prolonged period has shortened the lifetime of PP composites. Thus, variety of fillers has been incorporated into PP matrix to improve thermal degradation stability. The effects of titania and nanosilica in PP reinforced with o...

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Main Authors: Abdullah, Luqman Chuah, Ching, Yern Chee, Goh, Kuan Yong, Nadarajah, Kalyani
Format: Article
Language:English
Published: 2013
Online Access:http://psasir.upm.edu.my/id/eprint/28428/
http://psasir.upm.edu.my/id/eprint/28428/1/Effect%20of%20Nanosilica%20and%20Titania%20on%20Thermal%20Stability%20of%20Polypropylene.pdf
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author Abdullah, Luqman Chuah
Ching, Yern Chee
Goh, Kuan Yong
Nadarajah, Kalyani
author_facet Abdullah, Luqman Chuah
Ching, Yern Chee
Goh, Kuan Yong
Nadarajah, Kalyani
author_sort Abdullah, Luqman Chuah
building UPM Institutional Repository
collection Online Access
description Degradation of polypropylene (PP) composites at elevated temperature for prolonged period has shortened the lifetime of PP composites. Thus, variety of fillers has been incorporated into PP matrix to improve thermal degradation stability. The effects of titania and nanosilica in PP reinforced with oil palm empty fruit bunch fibres (EFB) were investigated in this study. Mechanical properties of the samples were determined before and after thermal ageing. Morphology of the composite with varies fillers composition were analyzed using scanning electron microscope. The introduction of nanosilica into PP/EFB composite filled with titania has increased both the melting and glass transition temperature of PP. Chain splitting in molecular chains reduced with the incorporation of nanosilica and titania into PP and PP/FEB composites. The TGA study has showed that the addition of nanosilica has further enhanced the thermal stability effect of titania in PP/EFB composite. However, both the Izod impact strength and tensile strength of the composite reduced greatly after 20 days of thermal ageing.
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institution Universiti Putra Malaysia
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language English
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publishDate 2013
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spelling upm-284282016-02-11T06:04:41Z http://psasir.upm.edu.my/id/eprint/28428/ Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite Abdullah, Luqman Chuah Ching, Yern Chee Goh, Kuan Yong Nadarajah, Kalyani Degradation of polypropylene (PP) composites at elevated temperature for prolonged period has shortened the lifetime of PP composites. Thus, variety of fillers has been incorporated into PP matrix to improve thermal degradation stability. The effects of titania and nanosilica in PP reinforced with oil palm empty fruit bunch fibres (EFB) were investigated in this study. Mechanical properties of the samples were determined before and after thermal ageing. Morphology of the composite with varies fillers composition were analyzed using scanning electron microscope. The introduction of nanosilica into PP/EFB composite filled with titania has increased both the melting and glass transition temperature of PP. Chain splitting in molecular chains reduced with the incorporation of nanosilica and titania into PP and PP/FEB composites. The TGA study has showed that the addition of nanosilica has further enhanced the thermal stability effect of titania in PP/EFB composite. However, both the Izod impact strength and tensile strength of the composite reduced greatly after 20 days of thermal ageing. 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/28428/1/Effect%20of%20Nanosilica%20and%20Titania%20on%20Thermal%20Stability%20of%20Polypropylene.pdf Abdullah, Luqman Chuah and Ching, Yern Chee and Goh, Kuan Yong and Nadarajah, Kalyani (2013) Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite. Journal of Biobased Materials and Bioenergy, 7 (1). pp. 169-174. ISSN 1556-6560 http://dx.doi.org/10.1166/jbmb.2013.1281 10.1166/jbmb.2013.1281
spellingShingle Abdullah, Luqman Chuah
Ching, Yern Chee
Goh, Kuan Yong
Nadarajah, Kalyani
Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite
title Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite
title_full Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite
title_fullStr Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite
title_full_unstemmed Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite
title_short Effect of Nanosilica and Titania on Thermal Stability of Polypropylene/Oil Palm Empty Fruit Fibre Composite
title_sort effect of nanosilica and titania on thermal stability of polypropylene/oil palm empty fruit fibre composite
url http://psasir.upm.edu.my/id/eprint/28428/
http://psasir.upm.edu.my/id/eprint/28428/
http://psasir.upm.edu.my/id/eprint/28428/
http://psasir.upm.edu.my/id/eprint/28428/1/Effect%20of%20Nanosilica%20and%20Titania%20on%20Thermal%20Stability%20of%20Polypropylene.pdf