Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter

The fractional crystallization behaviors of cocoa butter (CB) and enkabang fat (EF) in acetone were investigated. Melted samples of CB and EF were mixed separately with acetone in 1:2 a (w/v) ratio and partitioned into solid and liquid fractions under controlled temperature conditions. The isolated...

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Main Authors: Abdul Manaf, Yanty Noorzianna, Marikkar, Jalaldeen Mohammed Nazrim, Mustafa, Shuhaimi
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Cientificas 2013
Online Access:http://psasir.upm.edu.my/id/eprint/28087/
http://psasir.upm.edu.my/id/eprint/28087/1/28087.pdf
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author Abdul Manaf, Yanty Noorzianna
Marikkar, Jalaldeen Mohammed Nazrim
Mustafa, Shuhaimi
author_facet Abdul Manaf, Yanty Noorzianna
Marikkar, Jalaldeen Mohammed Nazrim
Mustafa, Shuhaimi
author_sort Abdul Manaf, Yanty Noorzianna
building UPM Institutional Repository
collection Online Access
description The fractional crystallization behaviors of cocoa butter (CB) and enkabang fat (EF) in acetone were investigated. Melted samples of CB and EF were mixed separately with acetone in 1:2 a (w/v) ratio and partitioned into solid and liquid fractions under controlled temperature conditions. The isolated fractions were compared to their respective native samples with respect to various physico-chemical parameters using standard chemical methods as well as instrumental techniques such as gas liquid chromatography (GLC), reversed-phase high performance liquid chromatography (RP-HPLC), and differential scanning calorimetry (DSC). According to the results, partitioning of either CB or EF under solvent assisted crystallization conditions yielded a major solid and a minor liquid fraction. The solid and liquid fractions of both fats were found to display many similarities, but few differences with regard to their composition and thermal properties. While the solid fractions may be useful as a hard stock in hard margarine and cosmetic product formulation, the liquid fraction would be useful as an ingredient for food applications.
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language English
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publisher Consejo Superior de Investigaciones Cientificas
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spelling upm-280872016-04-22T07:51:21Z http://psasir.upm.edu.my/id/eprint/28087/ Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter Abdul Manaf, Yanty Noorzianna Marikkar, Jalaldeen Mohammed Nazrim Mustafa, Shuhaimi The fractional crystallization behaviors of cocoa butter (CB) and enkabang fat (EF) in acetone were investigated. Melted samples of CB and EF were mixed separately with acetone in 1:2 a (w/v) ratio and partitioned into solid and liquid fractions under controlled temperature conditions. The isolated fractions were compared to their respective native samples with respect to various physico-chemical parameters using standard chemical methods as well as instrumental techniques such as gas liquid chromatography (GLC), reversed-phase high performance liquid chromatography (RP-HPLC), and differential scanning calorimetry (DSC). According to the results, partitioning of either CB or EF under solvent assisted crystallization conditions yielded a major solid and a minor liquid fraction. The solid and liquid fractions of both fats were found to display many similarities, but few differences with regard to their composition and thermal properties. While the solid fractions may be useful as a hard stock in hard margarine and cosmetic product formulation, the liquid fraction would be useful as an ingredient for food applications. Consejo Superior de Investigaciones Cientificas 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/28087/1/28087.pdf Abdul Manaf, Yanty Noorzianna and Marikkar, Jalaldeen Mohammed Nazrim and Mustafa, Shuhaimi (2013) Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter. Grasas y Aceites, 64 (5). pp. 546-553. ISSN 0017-3495; ESSN: 1988-4214 http://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/viewArticle/1461 10.3989/gya.023213
spellingShingle Abdul Manaf, Yanty Noorzianna
Marikkar, Jalaldeen Mohammed Nazrim
Mustafa, Shuhaimi
Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter
title Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter
title_full Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter
title_fullStr Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter
title_full_unstemmed Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter
title_short Effect of fractional crystallization on composition and thermal properties of engkabang (Shorea macrophylla) seed fat and cocoa butter
title_sort effect of fractional crystallization on composition and thermal properties of engkabang (shorea macrophylla) seed fat and cocoa butter
url http://psasir.upm.edu.my/id/eprint/28087/
http://psasir.upm.edu.my/id/eprint/28087/
http://psasir.upm.edu.my/id/eprint/28087/
http://psasir.upm.edu.my/id/eprint/28087/1/28087.pdf