Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts.

0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides were initially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied via XRD, TEM, XRF and BET method and their photoactivity was eva...

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Main Authors: Razali, Nor Zafirah, Abdullah, Abdul Halim, Haron, Md. Jelas
Format: Article
Language:English
English
Published: 2011
Online Access:http://psasir.upm.edu.my/id/eprint/25182/
http://psasir.upm.edu.my/id/eprint/25182/1/Degradation%20of%20methyl%20orange%20mediated%20by%20CuO.pdf
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author Razali, Nor Zafirah
Abdullah, Abdul Halim
Haron, Md. Jelas
author_facet Razali, Nor Zafirah
Abdullah, Abdul Halim
Haron, Md. Jelas
author_sort Razali, Nor Zafirah
building UPM Institutional Repository
collection Online Access
description 0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides were initially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied via XRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The properties of ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionally with CuO. In a photoactivity study, 1.0% CuO-ZnO photocatalyst has the highest degradation rate with the optimum mass loading of 1.5 g L-1. Increasing the initial concentration of MO reduced photocatalysts' photoactivity. The degradation of MO followed the pseudo-first order reaction. The photoactivity of CuO-ZnO was maintained until the fifth cycle, which indicates that it is a very stable compound.
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spelling upm-251822015-10-30T08:29:47Z http://psasir.upm.edu.my/id/eprint/25182/ Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts. Razali, Nor Zafirah Abdullah, Abdul Halim Haron, Md. Jelas 0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides were initially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied via XRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The properties of ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionally with CuO. In a photoactivity study, 1.0% CuO-ZnO photocatalyst has the highest degradation rate with the optimum mass loading of 1.5 g L-1. Increasing the initial concentration of MO reduced photocatalysts' photoactivity. The degradation of MO followed the pseudo-first order reaction. The photoactivity of CuO-ZnO was maintained until the fifth cycle, which indicates that it is a very stable compound. 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25182/1/Degradation%20of%20methyl%20orange%20mediated%20by%20CuO.pdf Razali, Nor Zafirah and Abdullah, Abdul Halim and Haron, Md. Jelas (2011) Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts. Environmental Engineering and Management Journal, 10 (10). pp. 1523-1528. ISSN 1582-9596 English
spellingShingle Razali, Nor Zafirah
Abdullah, Abdul Halim
Haron, Md. Jelas
Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts.
title Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts.
title_full Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts.
title_fullStr Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts.
title_full_unstemmed Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts.
title_short Degradation of methyl orange mediated by CuO-doped ZnO phoycatalysts.
title_sort degradation of methyl orange mediated by cuo-doped zno phoycatalysts.
url http://psasir.upm.edu.my/id/eprint/25182/
http://psasir.upm.edu.my/id/eprint/25182/1/Degradation%20of%20methyl%20orange%20mediated%20by%20CuO.pdf