Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.
The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2003
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| Online Access: | http://psasir.upm.edu.my/id/eprint/25097/ http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf |
| _version_ | 1848845216205766656 |
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| author | Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. |
| author_facet | Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. |
| author_sort | Crouse, Karen Anne |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b. |
| first_indexed | 2025-11-15T08:43:17Z |
| format | Article |
| id | upm-25097 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:43:17Z |
| publishDate | 2003 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-250972015-11-27T02:29:33Z http://psasir.upm.edu.my/id/eprint/25097/ Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b. International Union of Crystallography 2003-02 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf Crouse, Karen Anne and Kar , Teng Chew and Yamin, Bohari M. and Seik, Weng Ng and Tarafder, M.T.H. (2003) Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. Acta Crystallographica Section E: Structure Reports Online, 59 (2). o148-o150. ISSN 1600-5368 http://www.iucr.org/ 10.1107/S160053680300014X English |
| spellingShingle | Crouse, Karen Anne Kar , Teng Chew Yamin, Bohari M. Seik, Weng Ng Tarafder, M.T.H. Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
| title | Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
| title_full | Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
| title_fullStr | Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
| title_full_unstemmed | Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
| title_short | Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
| title_sort | hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. |
| url | http://psasir.upm.edu.my/id/eprint/25097/ http://psasir.upm.edu.my/id/eprint/25097/ http://psasir.upm.edu.my/id/eprint/25097/ http://psasir.upm.edu.my/id/eprint/25097/1/Hydrazine%20carbodithioic%20acid%20pyridinium.pdf |