(20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne.
The title dammarane triterpenoid, C30H50O4, assigned the name chrysura, was isolated from an ethyl acetate extract of Walsura chrysogyne leaves (Meliaceae). It has 20S*,24S* relative stereochemistry and an oxepanone ring with two methyl groups at position 4. The two cyclohexane rings adopt chair co...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2011
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/25048/ http://psasir.upm.edu.my/id/eprint/25048/1/20S.pdf |
| _version_ | 1848845203705692160 |
|---|---|
| author | Mahmod, Ilya Iryani Huey, Chong Kwong Mohamed Tahir, Mohamed Ibrahim Ismail, Intan Safinar |
| author_facet | Mahmod, Ilya Iryani Huey, Chong Kwong Mohamed Tahir, Mohamed Ibrahim Ismail, Intan Safinar |
| author_sort | Mahmod, Ilya Iryani |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The title dammarane triterpenoid, C30H50O4, assigned the name chrysura, was isolated from an ethyl acetate extract of Walsura chrysogyne leaves (Meliaceae). It has 20S*,24S* relative stereochemistry and an oxepanone ring with two methyl groups at position 4. The two cyclohexane rings adopt chair conformations. The cyclopentane and tetrahydrofuran rings have envelope conformations; their mean planes make a dihedral angle of 13.1 (3)°, indicating that the rings are only slightly tilted with respect to each other. There is an intramolecular C—H(...)O hydrogen bond in the molecule, which forms S(6) and S(7) ring motifs. In the crystal, molecules are linked via O—H(...)O and C—H(...)O hydrogen bonds, forming chains propagating along [001] which stack along the b-axis direction. |
| first_indexed | 2025-11-15T08:43:05Z |
| format | Article |
| id | upm-25048 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:43:05Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-250482015-10-09T09:00:27Z http://psasir.upm.edu.my/id/eprint/25048/ (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. Mahmod, Ilya Iryani Huey, Chong Kwong Mohamed Tahir, Mohamed Ibrahim Ismail, Intan Safinar The title dammarane triterpenoid, C30H50O4, assigned the name chrysura, was isolated from an ethyl acetate extract of Walsura chrysogyne leaves (Meliaceae). It has 20S*,24S* relative stereochemistry and an oxepanone ring with two methyl groups at position 4. The two cyclohexane rings adopt chair conformations. The cyclopentane and tetrahydrofuran rings have envelope conformations; their mean planes make a dihedral angle of 13.1 (3)°, indicating that the rings are only slightly tilted with respect to each other. There is an intramolecular C—H(...)O hydrogen bond in the molecule, which forms S(6) and S(7) ring motifs. In the crystal, molecules are linked via O—H(...)O and C—H(...)O hydrogen bonds, forming chains propagating along [001] which stack along the b-axis direction. International Union of Crystallography 2011-12-01 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25048/1/20S.pdf Mahmod, Ilya Iryani and Huey, Chong Kwong and Mohamed Tahir, Mohamed Ibrahim and Ismail, Intan Safinar (2011) (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. Acta Crystallographica Section E: Structure Reports Online, E67 (12). o3296. ISSN 1600-5368 http://www.iucr.org/ 10.1107/S1600536811047337 English |
| spellingShingle | Mahmod, Ilya Iryani Huey, Chong Kwong Mohamed Tahir, Mohamed Ibrahim Ismail, Intan Safinar (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. |
| title | (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. |
| title_full | (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. |
| title_fullStr | (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. |
| title_full_unstemmed | (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. |
| title_short | (20S *,24S *)-25-Hydroxy-20,24-epoxy-A-homo-4-oxadammaran-3-one (Chrysura) isolated from the leaves of Walsura chrysogyne. |
| title_sort | (20s *,24s *)-25-hydroxy-20,24-epoxy-a-homo-4-oxadammaran-3-one (chrysura) isolated from the leaves of walsura chrysogyne. |
| url | http://psasir.upm.edu.my/id/eprint/25048/ http://psasir.upm.edu.my/id/eprint/25048/ http://psasir.upm.edu.my/id/eprint/25048/ http://psasir.upm.edu.my/id/eprint/25048/1/20S.pdf |