{S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate.
The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central NiII ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedra...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012
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| Online Access: | http://psasir.upm.edu.my/id/eprint/25020/ |
| _version_ | 1848845195527847936 |
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| author | Omar, Siti Aminah Begum, Thahira Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne |
| author_facet | Omar, Siti Aminah Begum, Thahira Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne |
| author_sort | Omar, Siti Aminah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central NiII ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H(...)N and O—H(...)S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands. |
| first_indexed | 2025-11-15T08:42:57Z |
| format | Article |
| id | upm-25020 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T08:42:57Z |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-250202013-08-02T04:07:01Z http://psasir.upm.edu.my/id/eprint/25020/ {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. Omar, Siti Aminah Begum, Thahira Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central NiII ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H(...)N and O—H(...)S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands. International Union of Crystallography 2012-02-24 Article PeerReviewed Omar, Siti Aminah and Begum, Thahira and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne (2012) {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 68 (-). pp. 316-317. ISSN 1600-5368; ESSN:1600-5368 http://www.iucr.org/ 10.1107/S1600536812006952 English |
| spellingShingle | Omar, Siti Aminah Begum, Thahira Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. |
| title | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. |
| title_full | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. |
| title_fullStr | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. |
| title_full_unstemmed | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. |
| title_short | {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. |
| title_sort | {s-benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(ii) monohydrate. |
| url | http://psasir.upm.edu.my/id/eprint/25020/ http://psasir.upm.edu.my/id/eprint/25020/ http://psasir.upm.edu.my/id/eprint/25020/ |