(E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine.
In the structure of the title compound, C20H24N2S2, the central CN2S2 atoms are planar (r.m.s. deviation = 0.0205 Å) but both benzene rings are twisted out of this plane forming dihedral angles of 23.03 (6) and 84.75 (4)° (tolyl); the n-butyl group occupies a position normal to the plane [N—C—C—C t...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24957/ http://psasir.upm.edu.my/id/eprint/24957/1/E.pdf |
| _version_ | 1848845177660112896 |
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| author | Paulus, Georgiana Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_facet | Paulus, Georgiana Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_sort | Paulus, Georgiana |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | In the structure of the title compound, C20H24N2S2, the central CN2S2 atoms are planar (r.m.s. deviation = 0.0205 Å) but both benzene rings are twisted out of this plane forming dihedral angles of 23.03 (6) and 84.75 (4)° (tolyl); the n-butyl group occupies a position normal to the plane [N—C—C—C torsion angle = −84.33 (16)°]. The conformation of the imine bond [1.2888 (18) Å] is E. The syn arrangement of the thione S and amino H atoms enables the formation of N—H(...)S hydrogen bonds between centrosymmetrically related molecules. These lead to eight-membered {(...)HNC=S}2 synthons which are further stabilized by proximate C—H(...)S interactions. The resulting dimeric aggregates are connected into a supramolecular chain along the c axis by C—H(...)π(tolyl) interactions. |
| first_indexed | 2025-11-15T08:42:40Z |
| format | Article |
| id | upm-24957 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:42:40Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-249572015-10-28T07:29:48Z http://psasir.upm.edu.my/id/eprint/24957/ (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. Paulus, Georgiana Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. In the structure of the title compound, C20H24N2S2, the central CN2S2 atoms are planar (r.m.s. deviation = 0.0205 Å) but both benzene rings are twisted out of this plane forming dihedral angles of 23.03 (6) and 84.75 (4)° (tolyl); the n-butyl group occupies a position normal to the plane [N—C—C—C torsion angle = −84.33 (16)°]. The conformation of the imine bond [1.2888 (18) Å] is E. The syn arrangement of the thione S and amino H atoms enables the formation of N—H(...)S hydrogen bonds between centrosymmetrically related molecules. These lead to eight-membered {(...)HNC=S}2 synthons which are further stabilized by proximate C—H(...)S interactions. The resulting dimeric aggregates are connected into a supramolecular chain along the c axis by C—H(...)π(tolyl) interactions. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24957/1/E.pdf Paulus, Georgiana and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. Acta Crystallographica Section E: Structure Reports Online, 67 (6). pp. 1370-1383. ISSN 1600-5368; ESSN:1600-5368 http://www.iucr.org/ 10.1107/S1600536811016965 English |
| spellingShingle | Paulus, Georgiana Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. |
| title | (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. |
| title_full | (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. |
| title_fullStr | (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. |
| title_full_unstemmed | (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. |
| title_short | (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. |
| title_sort | (e)-[({[(3-methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. |
| url | http://psasir.upm.edu.my/id/eprint/24957/ http://psasir.upm.edu.my/id/eprint/24957/ http://psasir.upm.edu.my/id/eprint/24957/ http://psasir.upm.edu.my/id/eprint/24957/1/E.pdf |