2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate.
The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bo...
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| Format: | Article |
| Language: | English English |
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International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24955/ http://psasir.upm.edu.my/id/eprint/24955/1/2%20Naphthylmethyl.pdf |
| _version_ | 1848845177171476480 |
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| author | How, Fiona N.-F. Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_facet | How, Fiona N.-F. Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_sort | How, Fiona N.-F. |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bonds via[alpha]-N donor atoms and pyridyl N acceptor atoms into one-dimensional chains along the a axis. In addition, pairs of inversion-related dithiocarbazate groups and the attached pyridine groups are arranged with an interplanar distance 3.30 Å, leading to [pi]-[pi] stacking interactions. The crystal used for the structure determination was twinned.
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| first_indexed | 2025-11-15T08:42:40Z |
| format | Article |
| id | upm-24955 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:42:40Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-249552015-09-17T03:35:54Z http://psasir.upm.edu.my/id/eprint/24955/ 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. How, Fiona N.-F. Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bonds via[alpha]-N donor atoms and pyridyl N acceptor atoms into one-dimensional chains along the a axis. In addition, pairs of inversion-related dithiocarbazate groups and the attached pyridine groups are arranged with an interplanar distance 3.30 Å, leading to [pi]-[pi] stacking interactions. The crystal used for the structure determination was twinned. International Union of Crystallography 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24955/1/2%20Naphthylmethyl.pdf How, Fiona N.-F. and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 63 (7). pp. 3133-3134. ISSN 1600-5368; ESSN:1600-5368 http://www.iucr.org/ 10.1107/S1600536807025676 English |
| spellingShingle | How, Fiona N.-F. Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. |
| title | 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. |
| title_full | 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. |
| title_fullStr | 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. |
| title_full_unstemmed | 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. |
| title_short | 2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate. |
| title_sort | 2-naphthylmethyl n-(3-pyridylmethylene) hydrazinecarbodithioate. |
| url | http://psasir.upm.edu.my/id/eprint/24955/ http://psasir.upm.edu.my/id/eprint/24955/ http://psasir.upm.edu.my/id/eprint/24955/ http://psasir.upm.edu.my/id/eprint/24955/1/2%20Naphthylmethyl.pdf |