2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
The molecules in the crystal structure of the title compound, C19H17N3S2, are linked by an intermolecular N-H...N [2.839 (5) Å] hydrogen bond via the [alpha]-N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C-N bond but adopts...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24954/ http://psasir.upm.edu.my/id/eprint/24954/1/2.pdf |
| _version_ | 1848845176896749568 |
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| author | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_facet | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_sort | How, Fiona Ni Foong |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The molecules in the crystal structure of the title compound, C19H17N3S2, are linked by an intermolecular N-H...N [2.839 (5) Å] hydrogen bond via the [alpha]-N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C-N bond but adopts a cis position with respect to the naphthalene ring across the C-S bond. There is a [pi]-[pi] stacking interaction between the naphthalene rings, with a centroid-centroid distance of 3.397 (2) Å. |
| first_indexed | 2025-11-15T08:42:40Z |
| format | Article |
| id | upm-24954 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:42:40Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-249542015-09-17T03:26:47Z http://psasir.upm.edu.my/id/eprint/24954/ 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim The molecules in the crystal structure of the title compound, C19H17N3S2, are linked by an intermolecular N-H...N [2.839 (5) Å] hydrogen bond via the [alpha]-N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C-N bond but adopts a cis position with respect to the naphthalene ring across the C-S bond. There is a [pi]-[pi] stacking interaction between the naphthalene rings, with a centroid-centroid distance of 3.397 (2) Å. International Union of Crystallography 2007-07 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24954/1/2.pdf How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, E63 (7). pp. 3135-3136. ISSN 1600-5368; ESSN:1600-5368 http://www.iucr.org/ 10.1107/S1600536807025652 English |
| spellingShingle | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. |
| title | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. |
| title_full | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. |
| title_fullStr | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. |
| title_full_unstemmed | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. |
| title_short | 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. |
| title_sort | 2-naphthylmethyl n-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. |
| url | http://psasir.upm.edu.my/id/eprint/24954/ http://psasir.upm.edu.my/id/eprint/24954/ http://psasir.upm.edu.my/id/eprint/24954/ http://psasir.upm.edu.my/id/eprint/24954/1/2.pdf |