Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system.

Synthesis of Bi3Mg2Nb3O14 pyrochlore was carried out using conventional solid-state method. Phase formation and electrical properties of Bi3Mg2Nb3O14 pyrochlore were investigated by employment of different instruments. X-ray diffraction technique was applied to analyze the phase purity of the prepa...

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Main Authors: Tan, P. Y., Tan, Kar Ban, Khaw, C. C, Zainal, Zulkarnain, Chen, Soo Kien
Format: Article
Language:English
English
Published: Persatuan Sains dan Teknologi Keadaan Pepejal Malaysia 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24903/
http://psasir.upm.edu.my/id/eprint/24903/1/Synthesis%20and%20characterization%20of%20Bi3Mg2Nb3O14%20pyrochlore%20system.pdf
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author Tan, P. Y.
Tan, Kar Ban
Khaw, C. C
Zainal, Zulkarnain
Chen, Soo Kien
author_facet Tan, P. Y.
Tan, Kar Ban
Khaw, C. C
Zainal, Zulkarnain
Chen, Soo Kien
author_sort Tan, P. Y.
building UPM Institutional Repository
collection Online Access
description Synthesis of Bi3Mg2Nb3O14 pyrochlore was carried out using conventional solid-state method. Phase formation and electrical properties of Bi3Mg2Nb3O14 pyrochlore were investigated by employment of different instruments. X-ray diffraction technique was applied to analyze the phase purity of the prepared Bi3Mg2Nb3O14 pyrochlore. The surface morphology of Bi3Mg2Nb3O14 pyrochlore was examined by scanning electron microscope. Electrical properties of this sample were studied using ac impedance analyzer, HP4192A in the frequency range of 5 Hz – 13 MHz. The “ideal” Bi3Mg2Nb3O14 formed at 1025°C as cubic pyrochlore with minute traces of secondary phase. The dielectric constant was ~110 at room temperature at 1 MHz. The sample showed negative temperature coefficient of relative permittivity, TCε’ ~ -480 ppm/°C in the temperature range of 25 -300°C and low dielectric loss, tan δ, 10-3 at 1 MHz.
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language English
English
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publishDate 2011
publisher Persatuan Sains dan Teknologi Keadaan Pepejal Malaysia
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spelling upm-249032016-01-12T05:05:32Z http://psasir.upm.edu.my/id/eprint/24903/ Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system. Tan, P. Y. Tan, Kar Ban Khaw, C. C Zainal, Zulkarnain Chen, Soo Kien Synthesis of Bi3Mg2Nb3O14 pyrochlore was carried out using conventional solid-state method. Phase formation and electrical properties of Bi3Mg2Nb3O14 pyrochlore were investigated by employment of different instruments. X-ray diffraction technique was applied to analyze the phase purity of the prepared Bi3Mg2Nb3O14 pyrochlore. The surface morphology of Bi3Mg2Nb3O14 pyrochlore was examined by scanning electron microscope. Electrical properties of this sample were studied using ac impedance analyzer, HP4192A in the frequency range of 5 Hz – 13 MHz. The “ideal” Bi3Mg2Nb3O14 formed at 1025°C as cubic pyrochlore with minute traces of secondary phase. The dielectric constant was ~110 at room temperature at 1 MHz. The sample showed negative temperature coefficient of relative permittivity, TCε’ ~ -480 ppm/°C in the temperature range of 25 -300°C and low dielectric loss, tan δ, 10-3 at 1 MHz. Persatuan Sains dan Teknologi Keadaan Pepejal Malaysia 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24903/1/Synthesis%20and%20characterization%20of%20Bi3Mg2Nb3O14%20pyrochlore%20system.pdf Tan, P. Y. and Tan, Kar Ban and Khaw, C. C and Zainal, Zulkarnain and Chen, Soo Kien (2011) Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system. Solid State Science and Technology, 19 (2). pp. 221-231. ISSN 0128-7389 English
spellingShingle Tan, P. Y.
Tan, Kar Ban
Khaw, C. C
Zainal, Zulkarnain
Chen, Soo Kien
Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system.
title Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system.
title_full Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system.
title_fullStr Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system.
title_full_unstemmed Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system.
title_short Synthesis and characterization of Bi3Mg2Nb3O14 pyrochlore system.
title_sort synthesis and characterization of bi3mg2nb3o14 pyrochlore system.
url http://psasir.upm.edu.my/id/eprint/24903/
http://psasir.upm.edu.my/id/eprint/24903/1/Synthesis%20and%20characterization%20of%20Bi3Mg2Nb3O14%20pyrochlore%20system.pdf