Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.

Silver nanoparticles (AgNPs) of a small size were successfully synthesized using the wet chemical reduction method into the lamellar space layer of montmorillonite/chitosan (MMT/Cts) as an organomodified mineral solid support in the absence of any heat treatment. AgNO3, MMT, Cts, and NaBH4 were used...

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Main Authors: Shameli, Kamyar, Ahmad @ Ayob, Mansor, Zargar, Mohsen, Wan Yunus, Wan Md. Zin, Ibrahim, Nor Azowa, Shabanzadeh, Parvaneh, Moghaddam, Mansour Ghaffari
Format: Article
Language:English
Published: Dove Medical Press 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24804/
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author Shameli, Kamyar
Ahmad @ Ayob, Mansor
Zargar, Mohsen
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
Shabanzadeh, Parvaneh
Moghaddam, Mansour Ghaffari
author_facet Shameli, Kamyar
Ahmad @ Ayob, Mansor
Zargar, Mohsen
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
Shabanzadeh, Parvaneh
Moghaddam, Mansour Ghaffari
author_sort Shameli, Kamyar
building UPM Institutional Repository
collection Online Access
description Silver nanoparticles (AgNPs) of a small size were successfully synthesized using the wet chemical reduction method into the lamellar space layer of montmorillonite/chitosan (MMT/Cts) as an organomodified mineral solid support in the absence of any heat treatment. AgNO3, MMT, Cts, and NaBH4 were used as the silver precursor, the solid support, the natural polymeric stabilizer, and the chemical reduction agent, respectively. MMT was suspended in aqueous AgNO3/Cts solution. The interlamellar space limits were changed (d-spacing = 1.24-1.54 nm); therefore, AgNPs formed on the interlayer and external surface of MMT/Cts with d-average = 6.28-9.84 nm diameter. Characterizations were done using different methods, ie, ultraviolet-visible spectroscopy, powder X-ray diffraction, transmission electron microscopy, scanning electron microscopy, energy dispersive X-ray fluorescence spectrometry, and Fourier transform infrared spectroscopy. Silver/montmorillonite/chitosan bionanocomposite (Ag/MMT/Cts BNC) systems were examined. The antibacterial activity of AgNPs in MMT/Cts was investigated against Gram-positive bacteria, ie, Staphylococcus aureus and methicillin-resistant S. aureus and Gram-negative bacteria, ie, Escherichia coli, E. coli O157:H7, and Pseudomonas aeruginosa by the disc diffusion method using Mueller Hinton agar at different sizes of AgNPs. All of the synthesized Ag/MMT/Cts BNCs were found to have high antibacterial activity. These results show that Ag/MMT/Cts BNCs can be useful in different biological research and biomedical applications, including surgical devices and drug delivery vehicles.
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spelling upm-248042014-09-12T03:52:31Z http://psasir.upm.edu.my/id/eprint/24804/ Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity. Shameli, Kamyar Ahmad @ Ayob, Mansor Zargar, Mohsen Wan Yunus, Wan Md. Zin Ibrahim, Nor Azowa Shabanzadeh, Parvaneh Moghaddam, Mansour Ghaffari Silver nanoparticles (AgNPs) of a small size were successfully synthesized using the wet chemical reduction method into the lamellar space layer of montmorillonite/chitosan (MMT/Cts) as an organomodified mineral solid support in the absence of any heat treatment. AgNO3, MMT, Cts, and NaBH4 were used as the silver precursor, the solid support, the natural polymeric stabilizer, and the chemical reduction agent, respectively. MMT was suspended in aqueous AgNO3/Cts solution. The interlamellar space limits were changed (d-spacing = 1.24-1.54 nm); therefore, AgNPs formed on the interlayer and external surface of MMT/Cts with d-average = 6.28-9.84 nm diameter. Characterizations were done using different methods, ie, ultraviolet-visible spectroscopy, powder X-ray diffraction, transmission electron microscopy, scanning electron microscopy, energy dispersive X-ray fluorescence spectrometry, and Fourier transform infrared spectroscopy. Silver/montmorillonite/chitosan bionanocomposite (Ag/MMT/Cts BNC) systems were examined. The antibacterial activity of AgNPs in MMT/Cts was investigated against Gram-positive bacteria, ie, Staphylococcus aureus and methicillin-resistant S. aureus and Gram-negative bacteria, ie, Escherichia coli, E. coli O157:H7, and Pseudomonas aeruginosa by the disc diffusion method using Mueller Hinton agar at different sizes of AgNPs. All of the synthesized Ag/MMT/Cts BNCs were found to have high antibacterial activity. These results show that Ag/MMT/Cts BNCs can be useful in different biological research and biomedical applications, including surgical devices and drug delivery vehicles. Dove Medical Press 2011 Article PeerReviewed Shameli, Kamyar and Ahmad @ Ayob, Mansor and Zargar, Mohsen and Wan Yunus, Wan Md. Zin and Ibrahim, Nor Azowa and Shabanzadeh, Parvaneh and Moghaddam, Mansour Ghaffari (2011) Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity. International Journal of Nanomedicine, 6 (1). pp. 271-284. ISSN 1176-9114; ESSN:1178-2013 http://www.dovepress.com/ 10.2147/IJN.S16043 English
spellingShingle Shameli, Kamyar
Ahmad @ Ayob, Mansor
Zargar, Mohsen
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
Shabanzadeh, Parvaneh
Moghaddam, Mansour Ghaffari
Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.
title Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.
title_full Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.
title_fullStr Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.
title_full_unstemmed Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.
title_short Synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.
title_sort synthesis and characterization of silver/montmorillonite/ chitosan bionanocomposites by chemical reduction method and their antibacterial activity.
url http://psasir.upm.edu.my/id/eprint/24804/
http://psasir.upm.edu.my/id/eprint/24804/
http://psasir.upm.edu.my/id/eprint/24804/