(2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium.
The CdII atom in the title compound, [Cd(C5H 10NS2)2-(C10H8N 2)], exists in an N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H⋯S interactions, leading to...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
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International Union of Crystallography
2011
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24788/ http://psasir.upm.edu.my/id/eprint/24788/1/2.2%20Bipyridine.docx |
| _version_ | 1848845131956879360 |
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| author | Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_facet | Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_sort | Abdul Wahab, Nor Asiken |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The CdII atom in the title compound, [Cd(C5H 10NS2)2-(C10H8N 2)], exists in an N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H⋯S interactions, leading to linear supramolecular chains along the a axis. The primary connections between these are by π- π stacking interactions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å ]. Overall, the crystal structure may be described as comprising double layers of molecules that stack along the b axis. |
| first_indexed | 2025-11-15T08:41:57Z |
| format | Article |
| id | upm-24788 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:41:57Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-247882015-10-02T08:21:10Z http://psasir.upm.edu.my/id/eprint/24788/ (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The CdII atom in the title compound, [Cd(C5H 10NS2)2-(C10H8N 2)], exists in an N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H⋯S interactions, leading to linear supramolecular chains along the a axis. The primary connections between these are by π- π stacking interactions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å ]. Overall, the crystal structure may be described as comprising double layers of molecules that stack along the b axis. International Union of Crystallography 2011 Article PeerReviewed application/msword en http://psasir.upm.edu.my/id/eprint/24788/1/2.2%20Bipyridine.docx Abdul Wahab, Nor Asiken and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. Acta Crystallographica Section E: Structure Reports Online, 67. pp. 551-552. ISSN 1600-5368 10.1107/S1600536811012414 English |
| spellingShingle | Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. |
| title | (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. |
| title_full | (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. |
| title_fullStr | (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. |
| title_full_unstemmed | (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. |
| title_short | (2,2'-Bipyridine-k2N,N')bis(N-isopropyl-N-methyldithiocarbamato-k2S,S')-cadmium. |
| title_sort | (2,2'-bipyridine-k2n,n')bis(n-isopropyl-n-methyldithiocarbamato-k2s,s')-cadmium. |
| url | http://psasir.upm.edu.my/id/eprint/24788/ http://psasir.upm.edu.my/id/eprint/24788/ http://psasir.upm.edu.my/id/eprint/24788/1/2.2%20Bipyridine.docx |