(N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV).
The SnIV atom in the title diorganotin dithiocarbamate, [Sn(C4H9)2Cl(C10H12NS2)], is pentacoordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24785/ http://psasir.upm.edu.my/id/eprint/24785/1/N-benzyl-N.pdf |
| _version_ | 1848845131189321728 |
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| author | Abdul Mutalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_facet | Abdul Mutalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_sort | Abdul Mutalib, Amirah Faizah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The SnIV atom in the title diorganotin dithiocarbamate, [Sn(C4H9)2Cl(C10H12NS2)], is pentacoordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former. In the crystal structure, C-H...[pi] contacts link centrosymmetrically related molecules into dimeric aggregates. |
| first_indexed | 2025-11-15T08:41:56Z |
| format | Article |
| id | upm-24785 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:41:56Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-247852015-10-16T07:07:51Z http://psasir.upm.edu.my/id/eprint/24785/ (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). Abdul Mutalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The SnIV atom in the title diorganotin dithiocarbamate, [Sn(C4H9)2Cl(C10H12NS2)], is pentacoordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former. In the crystal structure, C-H...[pi] contacts link centrosymmetrically related molecules into dimeric aggregates. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24785/1/N-benzyl-N.pdf Abdul Mutalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). Acta Crystallographica Section E: Structure Reports Online, 67. pp. 372-373. ISSN 1600-5368 10.1107/S1600536811006398 English |
| spellingShingle | Abdul Mutalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). |
| title | (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). |
| title_full | (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). |
| title_fullStr | (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). |
| title_full_unstemmed | (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). |
| title_short | (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). |
| title_sort | (n-benzyl-n-ethyldithiocarbamato)di-tert-butylchloridotin(iv). |
| url | http://psasir.upm.edu.my/id/eprint/24785/ http://psasir.upm.edu.my/id/eprint/24785/ http://psasir.upm.edu.my/id/eprint/24785/1/N-benzyl-N.pdf |