Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode

Zinc oxide (ZnO) microparticles have been mechanically attached on the surface of a glassy carbon (GC) electrode. The purpose of this paper is to critically examine the modification of GC electrode with Zinc oxide microparticles and the effect on oxidation of paracetamol in 0.1 M KH2PO4 electrolyte...

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Main Authors: Mohammed Zidan, Tan, Wee Tee, Abdullah, Abdul Halim, Zainal, Zulkarnain, Goh, Joo Kheng
Format: Article
Language:English
Published: American-Eurasian Network for Scientific Information 2010
Online Access:http://psasir.upm.edu.my/id/eprint/24777/
http://psasir.upm.edu.my/id/eprint/24777/1/Electrocatalytic%20oxidation%20of%20paracetamol%20mediated%20by%20lithium%20doped%20microparticles%20Bi2O3.pdf
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author Mohammed Zidan,
Tan, Wee Tee
Abdullah, Abdul Halim
Zainal, Zulkarnain
Goh, Joo Kheng
author_facet Mohammed Zidan,
Tan, Wee Tee
Abdullah, Abdul Halim
Zainal, Zulkarnain
Goh, Joo Kheng
author_sort Mohammed Zidan,
building UPM Institutional Repository
collection Online Access
description Zinc oxide (ZnO) microparticles have been mechanically attached on the surface of a glassy carbon (GC) electrode. The purpose of this paper is to critically examine the modification of GC electrode with Zinc oxide microparticles and the effect on oxidation of paracetamol in 0.1 M KH2PO4 electrolyte solution by cyclic voltammetry (CV). Excellent electrocatalytic activity towards the oxidation of paracetamol was observed. Peak potential was observed to current was significantly enhanced by about 1.1 folds as compared to bare GC electrode shift slightly to less positive value by about 150 mV and. The sensitivity under conditions of cyclic voltammetry is significantly dependent on pH and scan rate. The variation of scan rate study shows that the system undergoes diffusioncontrolled process. In addition, calibration plot reveals linearity from the range 2.0 × 10-5 to 5.0 × 10-3M with a correlation coefficient of 0.997.
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institution Universiti Putra Malaysia
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language English
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publishDate 2010
publisher American-Eurasian Network for Scientific Information
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spelling upm-247772018-09-24T07:19:02Z http://psasir.upm.edu.my/id/eprint/24777/ Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode Mohammed Zidan, Tan, Wee Tee Abdullah, Abdul Halim Zainal, Zulkarnain Goh, Joo Kheng Zinc oxide (ZnO) microparticles have been mechanically attached on the surface of a glassy carbon (GC) electrode. The purpose of this paper is to critically examine the modification of GC electrode with Zinc oxide microparticles and the effect on oxidation of paracetamol in 0.1 M KH2PO4 electrolyte solution by cyclic voltammetry (CV). Excellent electrocatalytic activity towards the oxidation of paracetamol was observed. Peak potential was observed to current was significantly enhanced by about 1.1 folds as compared to bare GC electrode shift slightly to less positive value by about 150 mV and. The sensitivity under conditions of cyclic voltammetry is significantly dependent on pH and scan rate. The variation of scan rate study shows that the system undergoes diffusioncontrolled process. In addition, calibration plot reveals linearity from the range 2.0 × 10-5 to 5.0 × 10-3M with a correlation coefficient of 0.997. American-Eurasian Network for Scientific Information 2010-12 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24777/1/Electrocatalytic%20oxidation%20of%20paracetamol%20mediated%20by%20lithium%20doped%20microparticles%20Bi2O3.pdf Mohammed Zidan, and Tan, Wee Tee and Abdullah, Abdul Halim and Zainal, Zulkarnain and Goh, Joo Kheng (2010) Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode. Australian Journal of Basic and Applied Sciences, 4 (12). pp. 6025-6030. ISSN 1991-8178 http://www.ajbasweb.com/old/ajbas_December_2010.html
spellingShingle Mohammed Zidan,
Tan, Wee Tee
Abdullah, Abdul Halim
Zainal, Zulkarnain
Goh, Joo Kheng
Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode
title Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode
title_full Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode
title_fullStr Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode
title_full_unstemmed Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode
title_short Electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode
title_sort electrochemical oxidation of paracetamol mediated by zinc oxide modified glassy carbon electrode
url http://psasir.upm.edu.my/id/eprint/24777/
http://psasir.upm.edu.my/id/eprint/24777/
http://psasir.upm.edu.my/id/eprint/24777/1/Electrocatalytic%20oxidation%20of%20paracetamol%20mediated%20by%20lithium%20doped%20microparticles%20Bi2O3.pdf