Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu

Thermal inactivation kinetics for the purified membrane-bound polyphenol oxidases (mPPOs) and peroxidases (mPODs) isolated from Metroxylon sagu were analyzed. Each isoenzyme was treated at different time-temperature combinations in the range of 0-70min and 20-70C. Thermal inactivation rates constant...

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Main Authors: Onsa, Galila Hassan, Abdul Hamid, Azizah, Selamat, Jinap, Bakar, Jamilah, Abd Manap, Mohd Yazid, Saari, Nazamid
Format: Article
Language:English
Published: Wiley Periodicals 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24141/
http://psasir.upm.edu.my/id/eprint/24141/1/Analysis%20of%20thermal%20inactivation%20kinetics%20of%20membrane.pdf
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author Onsa, Galila Hassan
Abdul Hamid, Azizah
Selamat, Jinap
Bakar, Jamilah
Abd Manap, Mohd Yazid
Saari, Nazamid
author_facet Onsa, Galila Hassan
Abdul Hamid, Azizah
Selamat, Jinap
Bakar, Jamilah
Abd Manap, Mohd Yazid
Saari, Nazamid
author_sort Onsa, Galila Hassan
building UPM Institutional Repository
collection Online Access
description Thermal inactivation kinetics for the purified membrane-bound polyphenol oxidases (mPPOs) and peroxidases (mPODs) isolated from Metroxylon sagu were analyzed. Each isoenzyme was treated at different time-temperature combinations in the range of 0-70min and 20-70C. Thermal inactivation rates constant (k) at 70C for mPOD-I (72.9×10 -3/min) and mPOD-II (97.9×10 -3/min) were lower than that of mPPO-I (379.7×10 -3/min) and mPPO-II (138.1×10 -3/min). The activation energy for inactivation of mPPO-I (32.94kcal/mol) and mPPO-II (40.34kcal/mol) was lower compared with mPOD-I (45.77kcal/mol) and mPOD-II (40.62kcal/mol). The enthalpy values for mPOD-I (45.08kcal/mol) and mPOD-II (39.94kcal/mol) were higher than those of mPPOs (mPPO-I, 32.26kcal/mol; mPPO-II, 39.66kcal/mol). This result implies that both mPOD-I and mPOD-II are more thermostable.
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spelling upm-241412016-12-23T08:28:20Z http://psasir.upm.edu.my/id/eprint/24141/ Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu Onsa, Galila Hassan Abdul Hamid, Azizah Selamat, Jinap Bakar, Jamilah Abd Manap, Mohd Yazid Saari, Nazamid Thermal inactivation kinetics for the purified membrane-bound polyphenol oxidases (mPPOs) and peroxidases (mPODs) isolated from Metroxylon sagu were analyzed. Each isoenzyme was treated at different time-temperature combinations in the range of 0-70min and 20-70C. Thermal inactivation rates constant (k) at 70C for mPOD-I (72.9×10 -3/min) and mPOD-II (97.9×10 -3/min) were lower than that of mPPO-I (379.7×10 -3/min) and mPPO-II (138.1×10 -3/min). The activation energy for inactivation of mPPO-I (32.94kcal/mol) and mPPO-II (40.34kcal/mol) was lower compared with mPOD-I (45.77kcal/mol) and mPOD-II (40.62kcal/mol). The enthalpy values for mPOD-I (45.08kcal/mol) and mPOD-II (39.94kcal/mol) were higher than those of mPPOs (mPPO-I, 32.26kcal/mol; mPPO-II, 39.66kcal/mol). This result implies that both mPOD-I and mPOD-II are more thermostable. Wiley Periodicals 2011-06 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24141/1/Analysis%20of%20thermal%20inactivation%20kinetics%20of%20membrane.pdf Onsa, Galila Hassan and Abdul Hamid, Azizah and Selamat, Jinap and Bakar, Jamilah and Abd Manap, Mohd Yazid and Saari, Nazamid (2011) Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu. Journal of Food Biochemistry, 35 (3). pp. 819-832. ISSN 0145-8884; ESSN: 1745-4514 http://onlinelibrary.wiley.com/wol1/doi/10.1111/j.1745-4514.2010.00419.x/abstract 10.1111/j.1745-4514.2010.00419.x
spellingShingle Onsa, Galila Hassan
Abdul Hamid, Azizah
Selamat, Jinap
Bakar, Jamilah
Abd Manap, Mohd Yazid
Saari, Nazamid
Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu
title Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu
title_full Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu
title_fullStr Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu
title_full_unstemmed Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu
title_short Analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from Metroxylon sagu
title_sort analysis of thermal inactivation kinetics of membrane-bound polyphenol oxidases and peroxidases from metroxylon sagu
url http://psasir.upm.edu.my/id/eprint/24141/
http://psasir.upm.edu.my/id/eprint/24141/
http://psasir.upm.edu.my/id/eprint/24141/
http://psasir.upm.edu.my/id/eprint/24141/1/Analysis%20of%20thermal%20inactivation%20kinetics%20of%20membrane.pdf