Phase behavior of palm oil in blends with palm-based diacylglycerol

Phase behavior of palm oil (PO) in blends with different concentrations (10% intervals) of palm-based diacylglycerol oil (PO-DAG) was studied using the iso-solid diagram, solid fat content (SFC) with the hardness thermal protocol, DSC melting and crystallization curves, X-ray diffraction curves, and...

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Main Authors: Saberi, Amir Hoessein, Tan, Chin Ping, Lai, Oi Ming
Format: Article
Language:English
Published: Springer-Verlag 2011
Online Access:http://psasir.upm.edu.my/id/eprint/22418/
http://psasir.upm.edu.my/id/eprint/22418/1/Phase%20behavior%20of%20palm%20oil%20in%20blends%20with%20palm.pdf
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author Saberi, Amir Hoessein
Tan, Chin Ping
Lai, Oi Ming
author_facet Saberi, Amir Hoessein
Tan, Chin Ping
Lai, Oi Ming
author_sort Saberi, Amir Hoessein
building UPM Institutional Repository
collection Online Access
description Phase behavior of palm oil (PO) in blends with different concentrations (10% intervals) of palm-based diacylglycerol oil (PO-DAG) was studied using the iso-solid diagram, solid fat content (SFC) with the hardness thermal protocol, DSC melting and crystallization curves, X-ray diffraction curves, and texture analysis (hardness). Minor eutectic effects were observed at around 20–50% PO-DAG in 20–50% SFC iso-lines. The phase behavior predicted by the iso-solid diagram as well as SFC with the hardness thermal protocol did not account for hardness variations observed between PO and PO blends with 10–40% PO-DAG. Nevertheless, the latter could be attributed to the corresponding DSC data as well as crystal polymorphism. However, as the concentration of PO-DAG increased from 40% to 100%, iso-line temperatures, SFC with the hardness thermal protocol, and also hardness were found to steadily increase. PO-DAG at 10% concentration was found to have a β′-stabilizing effect on the polymorphism of PO, while a β-tending effect was observed as the concentration of PO-DAG increased from 10% to 90%.
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spelling upm-224182016-02-18T01:51:58Z http://psasir.upm.edu.my/id/eprint/22418/ Phase behavior of palm oil in blends with palm-based diacylglycerol Saberi, Amir Hoessein Tan, Chin Ping Lai, Oi Ming Phase behavior of palm oil (PO) in blends with different concentrations (10% intervals) of palm-based diacylglycerol oil (PO-DAG) was studied using the iso-solid diagram, solid fat content (SFC) with the hardness thermal protocol, DSC melting and crystallization curves, X-ray diffraction curves, and texture analysis (hardness). Minor eutectic effects were observed at around 20–50% PO-DAG in 20–50% SFC iso-lines. The phase behavior predicted by the iso-solid diagram as well as SFC with the hardness thermal protocol did not account for hardness variations observed between PO and PO blends with 10–40% PO-DAG. Nevertheless, the latter could be attributed to the corresponding DSC data as well as crystal polymorphism. However, as the concentration of PO-DAG increased from 40% to 100%, iso-line temperatures, SFC with the hardness thermal protocol, and also hardness were found to steadily increase. PO-DAG at 10% concentration was found to have a β′-stabilizing effect on the polymorphism of PO, while a β-tending effect was observed as the concentration of PO-DAG increased from 10% to 90%. Springer-Verlag 2011-12 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/22418/1/Phase%20behavior%20of%20palm%20oil%20in%20blends%20with%20palm.pdf Saberi, Amir Hoessein and Tan, Chin Ping and Lai, Oi Ming (2011) Phase behavior of palm oil in blends with palm-based diacylglycerol. Journal of the American Oil Chemists' Society, 88 (12). pp. 1857-1865. ISSN 0003-021X; ESSN: 1558-9331 http://link.springer.com/article/10.1007%2Fs11746-011-1860-6 10.1007/s11746-011-1860-6
spellingShingle Saberi, Amir Hoessein
Tan, Chin Ping
Lai, Oi Ming
Phase behavior of palm oil in blends with palm-based diacylglycerol
title Phase behavior of palm oil in blends with palm-based diacylglycerol
title_full Phase behavior of palm oil in blends with palm-based diacylglycerol
title_fullStr Phase behavior of palm oil in blends with palm-based diacylglycerol
title_full_unstemmed Phase behavior of palm oil in blends with palm-based diacylglycerol
title_short Phase behavior of palm oil in blends with palm-based diacylglycerol
title_sort phase behavior of palm oil in blends with palm-based diacylglycerol
url http://psasir.upm.edu.my/id/eprint/22418/
http://psasir.upm.edu.my/id/eprint/22418/
http://psasir.upm.edu.my/id/eprint/22418/
http://psasir.upm.edu.my/id/eprint/22418/1/Phase%20behavior%20of%20palm%20oil%20in%20blends%20with%20palm.pdf