Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts
Various high-energy modification and crystalline hydrates of Tutton's salts containing Mn(II), Ni(II) and Zn(II) have been prepared and their heats of solution measured. The energy difference of the anhydrous salts given in kJ/mole of hexahydrate have been assigned as 10Dqs for the complexes....
| Main Authors: | , , |
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| Format: | Article |
| Language: | English English |
| Published: |
1980
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| Online Access: | http://psasir.upm.edu.my/id/eprint/2077/ http://psasir.upm.edu.my/id/eprint/2077/1/Thermochemical_measurement_of_the.pdf |
| _version_ | 1848839144112914432 |
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| author | Muhammad, Badri Ibrahim, W. Crouse, Karen Anne |
| author_facet | Muhammad, Badri Ibrahim, W. Crouse, Karen Anne |
| author_sort | Muhammad, Badri |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Various high-energy modification and crystalline hydrates of Tutton's salts containing Mn(II), Ni(II)
and Zn(II) have been prepared and their heats of solution measured. The energy difference of the anhydrous
salts given in kJ/mole of hexahydrate have been assigned as 10Dqs for the complexes. The values obtained
have been compared with the ligand field splitting energies of the complexes in the sulphate salts. The discrepancies
were explained in terms of the presence of ammonium ions in the lattice which may have reduced the
electron density on the coordinated water molecules. |
| first_indexed | 2025-11-15T07:06:46Z |
| format | Article |
| id | upm-2077 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T07:06:46Z |
| publishDate | 1980 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-20772013-05-27T06:58:40Z http://psasir.upm.edu.my/id/eprint/2077/ Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts Muhammad, Badri Ibrahim, W. Crouse, Karen Anne Various high-energy modification and crystalline hydrates of Tutton's salts containing Mn(II), Ni(II) and Zn(II) have been prepared and their heats of solution measured. The energy difference of the anhydrous salts given in kJ/mole of hexahydrate have been assigned as 10Dqs for the complexes. The values obtained have been compared with the ligand field splitting energies of the complexes in the sulphate salts. The discrepancies were explained in terms of the presence of ammonium ions in the lattice which may have reduced the electron density on the coordinated water molecules. 1980 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/2077/1/Thermochemical_measurement_of_the.pdf Muhammad, Badri and Ibrahim, W. and Crouse, Karen Anne (1980) Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts. Pertanika, 3 (2). pp. 148-154. English |
| spellingShingle | Muhammad, Badri Ibrahim, W. Crouse, Karen Anne Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts |
| title | Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts |
| title_full | Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts |
| title_fullStr | Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts |
| title_full_unstemmed | Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts |
| title_short | Thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of Mn (II), Ni (II) and Zn (II) ions in the Tutton's salts |
| title_sort | thermochemical measurement of the ligand field splitting energies for hexaaquo complexes of mn (ii), ni (ii) and zn (ii) ions in the tutton's salts |
| url | http://psasir.upm.edu.my/id/eprint/2077/ http://psasir.upm.edu.my/id/eprint/2077/1/Thermochemical_measurement_of_the.pdf |