The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid

Intercalation of beneficial anion into inorganic host has lead to an opportunity to synthesize various combinations of new organic–inorganic nanohybrids with various potential applications; especially, for the controlled release formulation and storage purposes. Investigation on the release behavio...

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Main Authors: Hussein, Mohd Zobir, Muhammad Jaafar, Adilah, Yahya, Asmah, Zainal, Zulkarnain
Format: Article
Language:English
English
Published: SpringerOpen 2009
Subjects:
Online Access:http://psasir.upm.edu.my/id/eprint/17113/
http://psasir.upm.edu.my/id/eprint/17113/1/The%20effect%20of%20single.pdf
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author Hussein, Mohd Zobir
Muhammad Jaafar, Adilah
Yahya, Asmah
Zainal, Zulkarnain
author_facet Hussein, Mohd Zobir
Muhammad Jaafar, Adilah
Yahya, Asmah
Zainal, Zulkarnain
author_sort Hussein, Mohd Zobir
building UPM Institutional Repository
collection Online Access
description Intercalation of beneficial anion into inorganic host has lead to an opportunity to synthesize various combinations of new organic–inorganic nanohybrids with various potential applications; especially, for the controlled release formulation and storage purposes. Investigation on the release behavior of 2,4-dichlorophenoxyacetate (2,4-D)intercalated into the interlayer of Zn–Al-layered double hydroxide (ZAN) have been carried out using single, binary and ternary aqueous systems of chloride, carbonate and phosphate. The release behavior of the active agent 2,4-D from its double-layered hydroxide nanohybrid ZANDI was found to be of controlled manner governed by pseudosecond order kinetics. It was found that carbonate medium yielded the highest accumulated release of 2,4-D, while phosphate in combination with carbonate and/or nitrate speeds up the release rate of 2,4-D. These results indicate that it is possible to design and develop new delivery system of latex stimulant compound with controlled release property based on 2,4-D that is known as a substance to increase latex production of rubber tree, Hevea brasiliensis.
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spelling upm-171132015-09-17T00:05:24Z http://psasir.upm.edu.my/id/eprint/17113/ The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid Hussein, Mohd Zobir Muhammad Jaafar, Adilah Yahya, Asmah Zainal, Zulkarnain Intercalation of beneficial anion into inorganic host has lead to an opportunity to synthesize various combinations of new organic–inorganic nanohybrids with various potential applications; especially, for the controlled release formulation and storage purposes. Investigation on the release behavior of 2,4-dichlorophenoxyacetate (2,4-D)intercalated into the interlayer of Zn–Al-layered double hydroxide (ZAN) have been carried out using single, binary and ternary aqueous systems of chloride, carbonate and phosphate. The release behavior of the active agent 2,4-D from its double-layered hydroxide nanohybrid ZANDI was found to be of controlled manner governed by pseudosecond order kinetics. It was found that carbonate medium yielded the highest accumulated release of 2,4-D, while phosphate in combination with carbonate and/or nitrate speeds up the release rate of 2,4-D. These results indicate that it is possible to design and develop new delivery system of latex stimulant compound with controlled release property based on 2,4-D that is known as a substance to increase latex production of rubber tree, Hevea brasiliensis. SpringerOpen 2009 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/17113/1/The%20effect%20of%20single.pdf Hussein, Mohd Zobir and Muhammad Jaafar, Adilah and Yahya, Asmah and Zainal, Zulkarnain (2009) The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid. Nanoscale Research Letters, 4 (11). pp. 1351-1357. ISSN 1931-7573 Anions Chemistry, Analytic 10.1007/s11671-009-9404-9 English
spellingShingle Anions
Chemistry, Analytic
Hussein, Mohd Zobir
Muhammad Jaafar, Adilah
Yahya, Asmah
Zainal, Zulkarnain
The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid
title The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid
title_full The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid
title_fullStr The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid
title_full_unstemmed The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid
title_short The effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the Zn-Al-layered double hydroxide nanohybrid
title_sort effect of single, binary and ternary anions of chloride, carbonate and phosphate on the release of 2,4-dichlorophenoxyacetate intercalated into the zn-al-layered double hydroxide nanohybrid
topic Anions
Chemistry, Analytic
url http://psasir.upm.edu.my/id/eprint/17113/
http://psasir.upm.edu.my/id/eprint/17113/
http://psasir.upm.edu.my/id/eprint/17113/1/The%20effect%20of%20single.pdf