Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method

Problem statement: Silver/Montmorillonite/Chitosan Bionanocomposites (Ag/MMT/Cts BNCs) have been synthesized by UV-irradiation reduction method in the absence of any reducing agent or heat treatment which is used to antibacterial application and medical devices. Approach: MMT, Chitosan and AgNO3 wer...

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Main Authors: Ahmad, Mansor, Shameli, Kamyar, Darroudi, Majid, Wan Yunus, Wan Md. Zin, Ibrahim, Nor Azowa
Format: Article
Language:English
Published: Science Publications 2009
Online Access:http://psasir.upm.edu.my/id/eprint/16934/
http://psasir.upm.edu.my/id/eprint/16934/1/ajassp.2009.2030.2035.pdf
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author Ahmad, Mansor
Shameli, Kamyar
Darroudi, Majid
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
author_facet Ahmad, Mansor
Shameli, Kamyar
Darroudi, Majid
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
author_sort Ahmad, Mansor
building UPM Institutional Repository
collection Online Access
description Problem statement: Silver/Montmorillonite/Chitosan Bionanocomposites (Ag/MMT/Cts BNCs) have been synthesized by UV-irradiation reduction method in the absence of any reducing agent or heat treatment which is used to antibacterial application and medical devices. Approach: MMT, Chitosan and AgNO3 were used as a solid support, stabilizer and silver precursor, respectively. The properties of Ag/MMT/Cts BNCs were studied as a function of UV-irradiation times. The crystalline structure, d-spacing of interlayer of MMT, the size distributions and surface plasmon resonance of synthesized silver nanoparticles (Ag-NPs) were characterized using Powder X-Ray Diffraction (PXRD), Transmission Electron Microscopy (TEM) and UV-vis spectroscopy. The functional groups of prepared BNCs were also determined by Fourier Transform Infrared (FT-IR). Results: The results obtained from UV-vis spectroscopy of synthesized Ag-NPs showed that the intensity of the maximum wavelength of the plasmon peaks were increased with the increasing in the UV-irradiation times. Results from UV-visible spectroscopy and Transmission Electron Microscopy (TEM) microphotographs show that particles size of Ag-NPs decrease with the increase of UV-irradiation time. Conclusion: UV-irradiation disintegrated the Ag-NPs into smaller size until a relatively stable size and size distribution were achieved. Ag/MMT/Cts BNCs could be suitable to antimicrobial applications and medical devices.
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spelling upm-169342017-11-23T05:34:07Z http://psasir.upm.edu.my/id/eprint/16934/ Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method Ahmad, Mansor Shameli, Kamyar Darroudi, Majid Wan Yunus, Wan Md. Zin Ibrahim, Nor Azowa Problem statement: Silver/Montmorillonite/Chitosan Bionanocomposites (Ag/MMT/Cts BNCs) have been synthesized by UV-irradiation reduction method in the absence of any reducing agent or heat treatment which is used to antibacterial application and medical devices. Approach: MMT, Chitosan and AgNO3 were used as a solid support, stabilizer and silver precursor, respectively. The properties of Ag/MMT/Cts BNCs were studied as a function of UV-irradiation times. The crystalline structure, d-spacing of interlayer of MMT, the size distributions and surface plasmon resonance of synthesized silver nanoparticles (Ag-NPs) were characterized using Powder X-Ray Diffraction (PXRD), Transmission Electron Microscopy (TEM) and UV-vis spectroscopy. The functional groups of prepared BNCs were also determined by Fourier Transform Infrared (FT-IR). Results: The results obtained from UV-vis spectroscopy of synthesized Ag-NPs showed that the intensity of the maximum wavelength of the plasmon peaks were increased with the increasing in the UV-irradiation times. Results from UV-visible spectroscopy and Transmission Electron Microscopy (TEM) microphotographs show that particles size of Ag-NPs decrease with the increase of UV-irradiation time. Conclusion: UV-irradiation disintegrated the Ag-NPs into smaller size until a relatively stable size and size distribution were achieved. Ag/MMT/Cts BNCs could be suitable to antimicrobial applications and medical devices. Science Publications 2009 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/16934/1/ajassp.2009.2030.2035.pdf Ahmad, Mansor and Shameli, Kamyar and Darroudi, Majid and Wan Yunus, Wan Md. Zin and Ibrahim, Nor Azowa (2009) Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method. American Journal of Applied Sciences, 6 (12). pp. 2030-2035. ISSN 1546-9239; ESSN: 1554-3641 http://www.thescipub.com/abstract/10.3844/ajassp.2009.2030.2035 10.3844/ajassp.2009.2030.2035
spellingShingle Ahmad, Mansor
Shameli, Kamyar
Darroudi, Majid
Wan Yunus, Wan Md. Zin
Ibrahim, Nor Azowa
Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method
title Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method
title_full Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method
title_fullStr Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method
title_full_unstemmed Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method
title_short Synthesis and characterization of silver/clay/chitosan bionanocomposites by UV-irradiation method
title_sort synthesis and characterization of silver/clay/chitosan bionanocomposites by uv-irradiation method
url http://psasir.upm.edu.my/id/eprint/16934/
http://psasir.upm.edu.my/id/eprint/16934/
http://psasir.upm.edu.my/id/eprint/16934/
http://psasir.upm.edu.my/id/eprint/16934/1/ajassp.2009.2030.2035.pdf