Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite

Sorption of Cu(II) by zeolite sorbent chemically modified with hydroxamic acid (HASiZP) is described. The maximum sorption capacity of Cu(II) occurred at pH 5. Sorption capacity of Cu(II) by HASiZP was doubled compared to the original zeolite. Kinetic study shows that Cu(II) sorption followed by sec...

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Main Authors: Haron, Md. Jelas, Shafie, Nur Anisah, Yusof, Nor Azah, Kassim, Anuar, Wan Yunus, Wan Md. Zin, Talebi, S. M.
Format: Article
Language:English
Published: Malaysian Society of Analytical Sciences 2009
Online Access:http://psasir.upm.edu.my/id/eprint/16787/
http://psasir.upm.edu.my/id/eprint/16787/1/Sorption%20of%20Cu.pdf
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author Haron, Md. Jelas
Shafie, Nur Anisah
Yusof, Nor Azah
Kassim, Anuar
Wan Yunus, Wan Md. Zin
Talebi, S. M.
author_facet Haron, Md. Jelas
Shafie, Nur Anisah
Yusof, Nor Azah
Kassim, Anuar
Wan Yunus, Wan Md. Zin
Talebi, S. M.
author_sort Haron, Md. Jelas
building UPM Institutional Repository
collection Online Access
description Sorption of Cu(II) by zeolite sorbent chemically modified with hydroxamic acid (HASiZP) is described. The maximum sorption capacity of Cu(II) occurred at pH 5. Sorption capacity of Cu(II) by HASiZP was doubled compared to the original zeolite. Kinetic study shows that Cu(II) sorption followed by second order kinetic model. The sorption of Cu(II) followed Langmuir isotherm model with maximum capacity of 33.32 mg/g at 25°C and increased to 48.12 mg/g at 70°C. Cu(II) sorption by the HASiZP was endothermic and spontaneous processes with positive values of entropy changes.
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institution Universiti Putra Malaysia
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language English
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publishDate 2009
publisher Malaysian Society of Analytical Sciences
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spelling upm-167872015-09-15T07:36:10Z http://psasir.upm.edu.my/id/eprint/16787/ Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite Haron, Md. Jelas Shafie, Nur Anisah Yusof, Nor Azah Kassim, Anuar Wan Yunus, Wan Md. Zin Talebi, S. M. Sorption of Cu(II) by zeolite sorbent chemically modified with hydroxamic acid (HASiZP) is described. The maximum sorption capacity of Cu(II) occurred at pH 5. Sorption capacity of Cu(II) by HASiZP was doubled compared to the original zeolite. Kinetic study shows that Cu(II) sorption followed by second order kinetic model. The sorption of Cu(II) followed Langmuir isotherm model with maximum capacity of 33.32 mg/g at 25°C and increased to 48.12 mg/g at 70°C. Cu(II) sorption by the HASiZP was endothermic and spontaneous processes with positive values of entropy changes. Malaysian Society of Analytical Sciences 2009 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/16787/1/Sorption%20of%20Cu.pdf Haron, Md. Jelas and Shafie, Nur Anisah and Yusof, Nor Azah and Kassim, Anuar and Wan Yunus, Wan Md. Zin and Talebi, S. M. (2009) Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite. The Malaysian Journal of Analytical Sciences, 13 (1). pp. 52-62. ISSN 1394-2506
spellingShingle Haron, Md. Jelas
Shafie, Nur Anisah
Yusof, Nor Azah
Kassim, Anuar
Wan Yunus, Wan Md. Zin
Talebi, S. M.
Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite
title Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite
title_full Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite
title_fullStr Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite
title_full_unstemmed Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite
title_short Sorption of Cu(II) by chemically grafted hydroxamic acid-zeolite
title_sort sorption of cu(ii) by chemically grafted hydroxamic acid-zeolite
url http://psasir.upm.edu.my/id/eprint/16787/
http://psasir.upm.edu.my/id/eprint/16787/1/Sorption%20of%20Cu.pdf