Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles.

Nanoparticle-size d cobalt ferrites (CoFe2O4) were prepared via high energy mechanical alloying using a Spex8000D mixer/mill and heat treatment. The starting raw materials Co3O4 and Fe3O4 were milled for 12 hours in air, molded into samples of toroidal and disc shape and subs equently sintered at va...

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Main Authors: Waje, Samaila Bawa, Hashim, Mansor, Wan Yusoff, Wan Daud, Abbas, Zulkifly
Format: Article
Language:English
English
Published: INSInet Publication 2009
Online Access:http://psasir.upm.edu.my/id/eprint/16192/
http://psasir.upm.edu.my/id/eprint/16192/1/Physical%20and%20magnetic%20characterization%20of%20polycrystalline%20cobalt%20ferrite.pdf
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author Waje, Samaila Bawa
Hashim, Mansor
Wan Yusoff, Wan Daud
Abbas, Zulkifly
author_facet Waje, Samaila Bawa
Hashim, Mansor
Wan Yusoff, Wan Daud
Abbas, Zulkifly
author_sort Waje, Samaila Bawa
building UPM Institutional Repository
collection Online Access
description Nanoparticle-size d cobalt ferrites (CoFe2O4) were prepared via high energy mechanical alloying using a Spex8000D mixer/mill and heat treatment. The starting raw materials Co3O4 and Fe3O4 were milled for 12 hours in air, molded into samples of toroidal and disc shape and subs equently sintered at various temperatures from 600 to 1000 °C. The effect of sintering temperature on microstructure, magnetic and dielectric properties like saturation magnetic moment (Ms), coercivity (Hc), retentivity (Mr) permittivity and permeability were investigated in the frequency range 10 MHz to 1.8 GHz. The results show that single phase cobalt ferrites could not be formed during milling alone, however it formed at 600 °C. The crystallization of the cobalt ferrites was seen to increase strongly up to 1000°C. Further observed was that the crystallite size increased with the increasing sintering temperature. A high coercivity of up to 1982 Oe and a magnetization of 47 emu/g were obtained after an optimized heat treatment at 800 and 900°C respectively.
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spelling upm-161922015-10-22T01:16:36Z http://psasir.upm.edu.my/id/eprint/16192/ Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles. Waje, Samaila Bawa Hashim, Mansor Wan Yusoff, Wan Daud Abbas, Zulkifly Nanoparticle-size d cobalt ferrites (CoFe2O4) were prepared via high energy mechanical alloying using a Spex8000D mixer/mill and heat treatment. The starting raw materials Co3O4 and Fe3O4 were milled for 12 hours in air, molded into samples of toroidal and disc shape and subs equently sintered at various temperatures from 600 to 1000 °C. The effect of sintering temperature on microstructure, magnetic and dielectric properties like saturation magnetic moment (Ms), coercivity (Hc), retentivity (Mr) permittivity and permeability were investigated in the frequency range 10 MHz to 1.8 GHz. The results show that single phase cobalt ferrites could not be formed during milling alone, however it formed at 600 °C. The crystallization of the cobalt ferrites was seen to increase strongly up to 1000°C. Further observed was that the crystallite size increased with the increasing sintering temperature. A high coercivity of up to 1982 Oe and a magnetization of 47 emu/g were obtained after an optimized heat treatment at 800 and 900°C respectively. INSInet Publication 2009 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/16192/1/Physical%20and%20magnetic%20characterization%20of%20polycrystalline%20cobalt%20ferrite.pdf Waje, Samaila Bawa and Hashim, Mansor and Wan Yusoff, Wan Daud and Abbas, Zulkifly (2009) Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles. Journal of Applied Sciences Research, 5 (10). pp. 1440-1444. ISSN 1816-157X English
spellingShingle Waje, Samaila Bawa
Hashim, Mansor
Wan Yusoff, Wan Daud
Abbas, Zulkifly
Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles.
title Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles.
title_full Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles.
title_fullStr Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles.
title_full_unstemmed Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles.
title_short Physical and magnetic characterization of polycrystalline cobalt ferrite (CoFe2O4) materials prepared via mechanically alloyed nanoparticles.
title_sort physical and magnetic characterization of polycrystalline cobalt ferrite (cofe2o4) materials prepared via mechanically alloyed nanoparticles.
url http://psasir.upm.edu.my/id/eprint/16192/
http://psasir.upm.edu.my/id/eprint/16192/1/Physical%20and%20magnetic%20characterization%20of%20polycrystalline%20cobalt%20ferrite.pdf