Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy.

Virgin coconut oil (VCO) may be adulterated with cheaper oils, such as palm oil (PO). Thus, the detection and quantification of VCO adulteration with PO was monitored using Fourier transform infrared (FTIR) spectroscopy, combined with chemometrics of partial least square (PLS) and discriminant analy...

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Main Authors: Rohman, A., Che Man, Yaakob
Format: Article
Language:English
English
Published: Wiley Periodicals, Inc. 2009
Online Access:http://psasir.upm.edu.my/id/eprint/15724/
http://psasir.upm.edu.my/id/eprint/15724/1/Monitoring%20of%20virgin%20coconut%20oil.pdf
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author Rohman, A.
Che Man, Yaakob
author_facet Rohman, A.
Che Man, Yaakob
author_sort Rohman, A.
building UPM Institutional Repository
collection Online Access
description Virgin coconut oil (VCO) may be adulterated with cheaper oils, such as palm oil (PO). Thus, the detection and quantification of VCO adulteration with PO was monitored using Fourier transform infrared (FTIR) spectroscopy, combined with chemometrics of partial least square (PLS) and discriminant analysis at frequency regions of 3,010–3,000, 1,660–1,650 and 1,120–1,105/cm. Attenuated total reflectance (ATR) measurements were made on pure VCO and that adulterated with varying concentrations of PO (0.5–50% w/w in VCO). PLS calibration exhibited a good relationship between actual and FTIR-predicted values with coefficient of determination (R2) of 0.999 and standard error of calibration of 0.533. The cross validation was performed by removing one standard at a time, and the final R2 value of 0.996 and standard error of prediction of 0.953 were obtained. The discriminant analysis using seven principal components was able to classify pure VCO and that adulterated with PO.
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spelling upm-157242015-10-30T02:15:29Z http://psasir.upm.edu.my/id/eprint/15724/ Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy. Rohman, A. Che Man, Yaakob Virgin coconut oil (VCO) may be adulterated with cheaper oils, such as palm oil (PO). Thus, the detection and quantification of VCO adulteration with PO was monitored using Fourier transform infrared (FTIR) spectroscopy, combined with chemometrics of partial least square (PLS) and discriminant analysis at frequency regions of 3,010–3,000, 1,660–1,650 and 1,120–1,105/cm. Attenuated total reflectance (ATR) measurements were made on pure VCO and that adulterated with varying concentrations of PO (0.5–50% w/w in VCO). PLS calibration exhibited a good relationship between actual and FTIR-predicted values with coefficient of determination (R2) of 0.999 and standard error of calibration of 0.533. The cross validation was performed by removing one standard at a time, and the final R2 value of 0.996 and standard error of prediction of 0.953 were obtained. The discriminant analysis using seven principal components was able to classify pure VCO and that adulterated with PO. Wiley Periodicals, Inc. 2009 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/15724/1/Monitoring%20of%20virgin%20coconut%20oil.pdf Rohman, A. and Che Man, Yaakob (2009) Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy. Journal of Food Lipids, 16 (4). pp. 618-628. ISSN 1745-4522 10.1111/j.1745-4522.2009.01170.x English
spellingShingle Rohman, A.
Che Man, Yaakob
Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy.
title Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy.
title_full Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy.
title_fullStr Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy.
title_full_unstemmed Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy.
title_short Monitoring of virgin coconut oil (VCO) adulteration with palm oil using fourier transform infrared spectroscopy.
title_sort monitoring of virgin coconut oil (vco) adulteration with palm oil using fourier transform infrared spectroscopy.
url http://psasir.upm.edu.my/id/eprint/15724/
http://psasir.upm.edu.my/id/eprint/15724/
http://psasir.upm.edu.my/id/eprint/15724/1/Monitoring%20of%20virgin%20coconut%20oil.pdf