Highly selective transformation of poly[(R)-3-hydroxybutyric acid] into trans-crotonic acid by catalytic thermal degradation.
Highly selective transformation of poly[(R)-3-hydroxybutyric acid] (PHB) into trans-crotonic acid was achieved by thermal degradation using Mg compounds: MgO and Mg(OH)2 as catalysts. Through catalytic action, not only the temperature and Ea value of degradation were lowered by 40–50 °C and 11–14 kJ...
| Main Authors: | Ariffin, Hidayah, Nishida, Haruo, Shirai, Yoshihito, Hassan, Mohd Ali |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
Elsevier
2010
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/15012/ http://psasir.upm.edu.my/id/eprint/15012/1/Highly%20selective%20transformation%20of%20poly.pdf |
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