Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent.
A new organic-clay material, in which the organic moiety is intercalated into the inorganic interlayer, was prepared using gallate anion (GA) as a guest, and Zn–Al-layered double hydroxide, as clay host. The ion-exchange technique was found to be effective for the intercalation process in the format...
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| Format: | Article |
| Language: | English English |
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Elsevier
2010
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| Online Access: | http://psasir.upm.edu.my/id/eprint/14839/ http://psasir.upm.edu.my/id/eprint/14839/1/Gallate.pdf |
| _version_ | 1848842508560236544 |
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| author | Ghotbi, Mohammad Yeganeh Hussein, Mohd. Zobir |
| author_facet | Ghotbi, Mohammad Yeganeh Hussein, Mohd. Zobir |
| author_sort | Ghotbi, Mohammad Yeganeh |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | A new organic-clay material, in which the organic moiety is intercalated into the inorganic interlayer, was prepared using gallate anion (GA) as a guest, and Zn–Al-layered double hydroxide, as clay host. The ion-exchange technique was found to be effective for the intercalation process in the formation of the compound. Although the basal spacings of the LDH and its intercalated product were fairly similar, FTIR, CHNS and TGA/DTG results indicated that the GA was actually intercalated into the interlayer of the host in parallel orientation. The resulting nanostructure material possessed a well ordered layered structure with 42.2% GA loading (w/w). The release of the anion from the interlayer of the intercalated compound was found to be of controlled manner, governed by the first order kinetic and it was also concentration dependent. The material has potential as a nano-storage of anticarcenogenic agent with controlled delivery capability. |
| first_indexed | 2025-11-15T08:00:15Z |
| format | Article |
| id | upm-14839 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T08:00:15Z |
| publishDate | 2010 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-148392015-11-27T08:13:15Z http://psasir.upm.edu.my/id/eprint/14839/ Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. Ghotbi, Mohammad Yeganeh Hussein, Mohd. Zobir A new organic-clay material, in which the organic moiety is intercalated into the inorganic interlayer, was prepared using gallate anion (GA) as a guest, and Zn–Al-layered double hydroxide, as clay host. The ion-exchange technique was found to be effective for the intercalation process in the formation of the compound. Although the basal spacings of the LDH and its intercalated product were fairly similar, FTIR, CHNS and TGA/DTG results indicated that the GA was actually intercalated into the interlayer of the host in parallel orientation. The resulting nanostructure material possessed a well ordered layered structure with 42.2% GA loading (w/w). The release of the anion from the interlayer of the intercalated compound was found to be of controlled manner, governed by the first order kinetic and it was also concentration dependent. The material has potential as a nano-storage of anticarcenogenic agent with controlled delivery capability. Elsevier 2010 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/14839/1/Gallate.pdf Ghotbi, Mohammad Yeganeh and Hussein, Mohd. Zobir (2010) Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. Journal of Physics and Chemistry of Solids, 71 (11). pp. 1565-1570. ISSN 0022-3697 10.1016/j.jpcs.2010.08.003 English |
| spellingShingle | Ghotbi, Mohammad Yeganeh Hussein, Mohd. Zobir Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. |
| title | Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. |
| title_full | Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. |
| title_fullStr | Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. |
| title_full_unstemmed | Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. |
| title_short | Gallate-Zn-Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. |
| title_sort | gallate-zn-al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent. |
| url | http://psasir.upm.edu.my/id/eprint/14839/ http://psasir.upm.edu.my/id/eprint/14839/ http://psasir.upm.edu.my/id/eprint/14839/1/Gallate.pdf |