Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD

Titanium dioxide (TiO2) nanoparticles were prepared via Metal Organic Chemical Vapour Deposition (MOCVD) technique at 400 and 700°C. Different amount of iron (Fe) dopant was introduced inside the MOCVD reactor along with the precursor to produce different Fe dopant concentrations of TiO2 nanoparticl...

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Main Authors: Othman, Siti Hajar, Abdul Rashid, Suraya, Mohd Ghazi, Tinia Idaty, Abdullah, Norhafizah
Format: Article
Language:English
Published: Asian Network for Scientific Information 2010
Online Access:http://psasir.upm.edu.my/id/eprint/14239/
http://psasir.upm.edu.my/id/eprint/14239/1/Effect%20of%20Fe%20doping%20on%20phase%20transition%20of%20TiO2%20nanoparticles%20synthesized%20by%20MOCVD.pdf
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author Othman, Siti Hajar
Abdul Rashid, Suraya
Mohd Ghazi, Tinia Idaty
Abdullah, Norhafizah
author_facet Othman, Siti Hajar
Abdul Rashid, Suraya
Mohd Ghazi, Tinia Idaty
Abdullah, Norhafizah
author_sort Othman, Siti Hajar
building UPM Institutional Repository
collection Online Access
description Titanium dioxide (TiO2) nanoparticles were prepared via Metal Organic Chemical Vapour Deposition (MOCVD) technique at 400 and 700°C. Different amount of iron (Fe) dopant was introduced inside the MOCVD reactor along with the precursor to produce different Fe dopant concentrations of TiO2 nanoparticles. Transmission Electron Microscope (TEM) results disclosed that increasing the deposition temperature resulted in a significant decrease of the size of TiO2 nanoparticle samples and a narrower size distribution. X-ray diffraction (XRD) results revealed that TiO2 nanoparticle sample deposited at 400°C was amorphous while the sample deposited at 700°C was in anatase crystal structure. Fe doping induced phase transition from amorphous to anatase for sample deposited at 400°C and from anatase to rutile for sample deposited at 700°C. Increased concentration of Fe dopant promoted both phase transitions. Meanwhile, TEM and XRD data disclosed that increased concentration of Fe dopant lead to a decrease in size of the nanoparticles produced.
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spelling upm-142392018-10-08T02:45:41Z http://psasir.upm.edu.my/id/eprint/14239/ Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD Othman, Siti Hajar Abdul Rashid, Suraya Mohd Ghazi, Tinia Idaty Abdullah, Norhafizah Titanium dioxide (TiO2) nanoparticles were prepared via Metal Organic Chemical Vapour Deposition (MOCVD) technique at 400 and 700°C. Different amount of iron (Fe) dopant was introduced inside the MOCVD reactor along with the precursor to produce different Fe dopant concentrations of TiO2 nanoparticles. Transmission Electron Microscope (TEM) results disclosed that increasing the deposition temperature resulted in a significant decrease of the size of TiO2 nanoparticle samples and a narrower size distribution. X-ray diffraction (XRD) results revealed that TiO2 nanoparticle sample deposited at 400°C was amorphous while the sample deposited at 700°C was in anatase crystal structure. Fe doping induced phase transition from amorphous to anatase for sample deposited at 400°C and from anatase to rutile for sample deposited at 700°C. Increased concentration of Fe dopant promoted both phase transitions. Meanwhile, TEM and XRD data disclosed that increased concentration of Fe dopant lead to a decrease in size of the nanoparticles produced. Asian Network for Scientific Information 2010 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/14239/1/Effect%20of%20Fe%20doping%20on%20phase%20transition%20of%20TiO2%20nanoparticles%20synthesized%20by%20MOCVD.pdf Othman, Siti Hajar and Abdul Rashid, Suraya and Mohd Ghazi, Tinia Idaty and Abdullah, Norhafizah (2010) Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD. Journal of Applied Sciences, 10 (12). pp. 1044-1051. ISSN 1812-5654; ESSN: 1812-5662 https://scialert.net/abstract/?doi=jas.2010.1044.1051 10.3923/jas.2010.1044.1051
spellingShingle Othman, Siti Hajar
Abdul Rashid, Suraya
Mohd Ghazi, Tinia Idaty
Abdullah, Norhafizah
Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD
title Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD
title_full Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD
title_fullStr Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD
title_full_unstemmed Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD
title_short Effect of Fe doping on phase transition of TiO2 nanoparticles synthesized by MOCVD
title_sort effect of fe doping on phase transition of tio2 nanoparticles synthesized by mocvd
url http://psasir.upm.edu.my/id/eprint/14239/
http://psasir.upm.edu.my/id/eprint/14239/
http://psasir.upm.edu.my/id/eprint/14239/
http://psasir.upm.edu.my/id/eprint/14239/1/Effect%20of%20Fe%20doping%20on%20phase%20transition%20of%20TiO2%20nanoparticles%20synthesized%20by%20MOCVD.pdf