Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5)

In this work, frequency-dependent dielectric properties of polycrystalline samples with nominal compositions FeTe1−x Se x (x = 0.0–0.5) were investigated. The samples were synthesized via solid-state reaction method with intermittent grinding at ambient pressure. The phase formation, lattice propert...

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Main Authors: Lim, Edmund Hua Hang, Liew, Josephine Ying Chyi, Awang Kechik, Mohd Mustafa, Shaari, Abdul Halim, Tan, Kar Ban, Lee, Oon Jew, Chen, Soo Kien
Format: Article
Language:English
Published: Springer 2017
Online Access:http://psasir.upm.edu.my/id/eprint/13442/
http://psasir.upm.edu.my/id/eprint/13442/1/Room%20temperature%20dielectric%20properties%20of%20polycrystalline.pdf
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author Lim, Edmund Hua Hang
Liew, Josephine Ying Chyi
Awang Kechik, Mohd Mustafa
Shaari, Abdul Halim
Tan, Kar Ban
Lee, Oon Jew
Chen, Soo Kien
author_facet Lim, Edmund Hua Hang
Liew, Josephine Ying Chyi
Awang Kechik, Mohd Mustafa
Shaari, Abdul Halim
Tan, Kar Ban
Lee, Oon Jew
Chen, Soo Kien
author_sort Lim, Edmund Hua Hang
building UPM Institutional Repository
collection Online Access
description In this work, frequency-dependent dielectric properties of polycrystalline samples with nominal compositions FeTe1−x Se x (x = 0.0–0.5) were investigated. The samples were synthesized via solid-state reaction method with intermittent grinding at ambient pressure. The phase formation, lattice properties and chemical compositions of the samples were analysed. Dielectric constants (ε′, ε′′), dielectric loss (tan δ) and alternating current (AC) conductivity (σ ac) as a function of frequency ranging from 100 Hz to 10 MHz were measured at room temperature. X-ray diffraction (XRD) data showed the presence of impurity phases of Fe3O4, FeTe2 and hexagonal FeSe/Fe7Se8. Both a and c lattice parameters decreased with the substitution of Se. Energy-dispersive x-ray spectroscopy confirmed the increasing ratio of Se/Te with x. The measured negative values of real dielectric constant (ε′) for x = 0.0–0.5 indicate the conductive nature of these samples. As the Se content was increased, the ε′ became more negative as a result of better grain connectivity as shown by the higher AC conductivity and dielectric loss.
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institution Universiti Putra Malaysia
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language English
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spelling upm-134422018-06-11T08:18:03Z http://psasir.upm.edu.my/id/eprint/13442/ Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5) Lim, Edmund Hua Hang Liew, Josephine Ying Chyi Awang Kechik, Mohd Mustafa Shaari, Abdul Halim Tan, Kar Ban Lee, Oon Jew Chen, Soo Kien In this work, frequency-dependent dielectric properties of polycrystalline samples with nominal compositions FeTe1−x Se x (x = 0.0–0.5) were investigated. The samples were synthesized via solid-state reaction method with intermittent grinding at ambient pressure. The phase formation, lattice properties and chemical compositions of the samples were analysed. Dielectric constants (ε′, ε′′), dielectric loss (tan δ) and alternating current (AC) conductivity (σ ac) as a function of frequency ranging from 100 Hz to 10 MHz were measured at room temperature. X-ray diffraction (XRD) data showed the presence of impurity phases of Fe3O4, FeTe2 and hexagonal FeSe/Fe7Se8. Both a and c lattice parameters decreased with the substitution of Se. Energy-dispersive x-ray spectroscopy confirmed the increasing ratio of Se/Te with x. The measured negative values of real dielectric constant (ε′) for x = 0.0–0.5 indicate the conductive nature of these samples. As the Se content was increased, the ε′ became more negative as a result of better grain connectivity as shown by the higher AC conductivity and dielectric loss. Springer 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/13442/1/Room%20temperature%20dielectric%20properties%20of%20polycrystalline.pdf Lim, Edmund Hua Hang and Liew, Josephine Ying Chyi and Awang Kechik, Mohd Mustafa and Shaari, Abdul Halim and Tan, Kar Ban and Lee, Oon Jew and Chen, Soo Kien (2017) Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5). Journal of Superconductivity and Novel Magnetism, 30 (10). pp. 2915-2920. ISSN 1557-1939; ESSN: 1557-1947 https://link.springer.com/article/10.1007%2Fs10948-017-4122-5 10.1007/s10948-017-4122-5
spellingShingle Lim, Edmund Hua Hang
Liew, Josephine Ying Chyi
Awang Kechik, Mohd Mustafa
Shaari, Abdul Halim
Tan, Kar Ban
Lee, Oon Jew
Chen, Soo Kien
Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5)
title Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5)
title_full Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5)
title_fullStr Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5)
title_full_unstemmed Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5)
title_short Room temperature dielectric properties of polycrystalline FeTe1−xSex (x = 0.0–0.5)
title_sort room temperature dielectric properties of polycrystalline fete1−xsex (x = 0.0–0.5)
url http://psasir.upm.edu.my/id/eprint/13442/
http://psasir.upm.edu.my/id/eprint/13442/
http://psasir.upm.edu.my/id/eprint/13442/
http://psasir.upm.edu.my/id/eprint/13442/1/Room%20temperature%20dielectric%20properties%20of%20polycrystalline.pdf