Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)
Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010
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| Online Access: | http://psasir.upm.edu.my/id/eprint/13428/ http://psasir.upm.edu.my/id/eprint/13428/1/Bis%20%28N-sec-butyl-N%29.pdf |
| _version_ | 1848842109944070144 |
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| author | Alzaalouk, Amna Salem Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward Richard Tom |
| author_facet | Alzaalouk, Amna Salem Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward Richard Tom |
| author_sort | Alzaalouk, Amna Salem |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5). |
| first_indexed | 2025-11-15T07:53:55Z |
| format | Article |
| id | upm-13428 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T07:53:55Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-134282015-10-22T06:29:42Z http://psasir.upm.edu.my/id/eprint/13428/ Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) Alzaalouk, Amna Salem Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward Richard Tom Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5). International Union of Crystallography 2010-09-01 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/13428/1/Bis%20%28N-sec-butyl-N%29.pdf Alzaalouk, Amna Salem and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Ng, Seik Weng and Tiekink, Edward Richard Tom (2010) Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (pt. 9). m1165-m1166. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?bt5329 10.1107/S160053681003367 |
| spellingShingle | Alzaalouk, Amna Salem Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward Richard Tom Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) |
| title | Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) |
| title_full | Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) |
| title_fullStr | Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) |
| title_full_unstemmed | Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) |
| title_short | Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) |
| title_sort | bis(n-sec-butyl-n-n-propyldithiocarbamato- 2s,s')(1,10-phenanthroline- 2n,n')zinc(ii) |
| url | http://psasir.upm.edu.my/id/eprint/13428/ http://psasir.upm.edu.my/id/eprint/13428/ http://psasir.upm.edu.my/id/eprint/13428/ http://psasir.upm.edu.my/id/eprint/13428/1/Bis%20%28N-sec-butyl-N%29.pdf |