(N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
The SnIV atom in the title organotin dithiocarbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate betwe...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2010
|
| Subjects: | |
| Online Access: | http://psasir.upm.edu.my/id/eprint/12627/ http://psasir.upm.edu.my/id/eprint/12627/1/N-benzy.pdf |
| _version_ | 1848841886150688768 |
|---|---|
| author | Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Seik, Weng Ng Tiekink, Edward R. T. |
| author_facet | Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Seik, Weng Ng Tiekink, Edward R. T. |
| author_sort | Abdul Muthalib, Amirah Faizah |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | The SnIV atom in the title organotin dithiocarbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intramolecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant intermolecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supramolecular arrays that stack along the b axis. |
| first_indexed | 2025-11-15T07:50:21Z |
| format | Article |
| id | upm-12627 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-15T07:50:21Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-126272015-11-03T01:07:04Z http://psasir.upm.edu.my/id/eprint/12627/ (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Seik, Weng Ng Tiekink, Edward R. T. The SnIV atom in the title organotin dithiocarbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intramolecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant intermolecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supramolecular arrays that stack along the b axis. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/12627/1/N-benzy.pdf Abdul Muthalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Seik, Weng Ng and Tiekink, Edward R. T. (2010) (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (1087). pp. 1-12. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536810031636 crystal English |
| spellingShingle | crystal Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Seik, Weng Ng Tiekink, Edward R. T. (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) |
| title | (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) |
| title_full | (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) |
| title_fullStr | (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) |
| title_full_unstemmed | (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) |
| title_short | (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) |
| title_sort | (n-benzyl-n-isopropyldithiocarbamato)-chloridodiphenyltin(iv) |
| topic | crystal |
| url | http://psasir.upm.edu.my/id/eprint/12627/ http://psasir.upm.edu.my/id/eprint/12627/ http://psasir.upm.edu.my/id/eprint/12627/1/N-benzy.pdf |