Influence of organic species on the characteristics of Mo-V oxide

This study investigates on the effect of organic species on the characteristics of molybdenum-vanadium mixed oxide catalysts. The MoV precursors were prepared by homogeneous precipitation method using urea hydrolysis. The oxides were later treated with three organic species namely polyvinyl alcoho...

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Main Authors: Woi, Pei Meng, Ramli, Irmawati, Yap, Taufiq Yun Hin
Format: Article
Language:English
Published: Malaysian Analytical Sciences Society 2007
Online Access:http://psasir.upm.edu.my/id/eprint/11936/
http://psasir.upm.edu.my/id/eprint/11936/1/Influenced%20of%20Organic%20Species%20on%20the%20Characteristics%20of%20Mo.pdf
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author Woi, Pei Meng
Ramli, Irmawati
Yap, Taufiq Yun Hin
author_facet Woi, Pei Meng
Ramli, Irmawati
Yap, Taufiq Yun Hin
author_sort Woi, Pei Meng
building UPM Institutional Repository
collection Online Access
description This study investigates on the effect of organic species on the characteristics of molybdenum-vanadium mixed oxide catalysts. The MoV precursors were prepared by homogeneous precipitation method using urea hydrolysis. The oxides were later treated with three organic species namely polyvinyl alcohol (PVA), malic acid (MA) and adipic acid (AA). The solutions were refluxed in a prescribed time. The solid obtained were calcined and subsequently denoted as MoV(PVA), MoV(MA) and MoV(AA). Interesting results in which high surface area values (SBET) were obtained in the range between 10 to 20 m2 g-1. XRD reckoned the samples are in highly crystalline form. H2-Temperature programmed reduction analysis showed that the total number of oxygen removed are 1.4 x 1022 atoms g-1, 3.3 x 1022 atoms g-1 and 1.8 x 1022 atoms g-1 for MoV(PVA), MoV(MA) and MoV(AA) respectively.
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spelling upm-119362016-11-23T09:19:51Z http://psasir.upm.edu.my/id/eprint/11936/ Influence of organic species on the characteristics of Mo-V oxide Woi, Pei Meng Ramli, Irmawati Yap, Taufiq Yun Hin This study investigates on the effect of organic species on the characteristics of molybdenum-vanadium mixed oxide catalysts. The MoV precursors were prepared by homogeneous precipitation method using urea hydrolysis. The oxides were later treated with three organic species namely polyvinyl alcohol (PVA), malic acid (MA) and adipic acid (AA). The solutions were refluxed in a prescribed time. The solid obtained were calcined and subsequently denoted as MoV(PVA), MoV(MA) and MoV(AA). Interesting results in which high surface area values (SBET) were obtained in the range between 10 to 20 m2 g-1. XRD reckoned the samples are in highly crystalline form. H2-Temperature programmed reduction analysis showed that the total number of oxygen removed are 1.4 x 1022 atoms g-1, 3.3 x 1022 atoms g-1 and 1.8 x 1022 atoms g-1 for MoV(PVA), MoV(MA) and MoV(AA) respectively. Malaysian Analytical Sciences Society 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/11936/1/Influenced%20of%20Organic%20Species%20on%20the%20Characteristics%20of%20Mo.pdf Woi, Pei Meng and Ramli, Irmawati and Yap, Taufiq Yun Hin (2007) Influence of organic species on the characteristics of Mo-V oxide. The Malaysian Journal of Analytical Sciences, 11 (1). pp. 160-165. ISSN 1394-2506 http://www.ukm.my/mjas/new_mjas/
spellingShingle Woi, Pei Meng
Ramli, Irmawati
Yap, Taufiq Yun Hin
Influence of organic species on the characteristics of Mo-V oxide
title Influence of organic species on the characteristics of Mo-V oxide
title_full Influence of organic species on the characteristics of Mo-V oxide
title_fullStr Influence of organic species on the characteristics of Mo-V oxide
title_full_unstemmed Influence of organic species on the characteristics of Mo-V oxide
title_short Influence of organic species on the characteristics of Mo-V oxide
title_sort influence of organic species on the characteristics of mo-v oxide
url http://psasir.upm.edu.my/id/eprint/11936/
http://psasir.upm.edu.my/id/eprint/11936/
http://psasir.upm.edu.my/id/eprint/11936/1/Influenced%20of%20Organic%20Species%20on%20the%20Characteristics%20of%20Mo.pdf